Nef-isocyanide-Perkow synthesis of new polarized olefins containing 2- dicyanomethylene-2,3-dihydrothiazole and 2-dicyanomethylene-1,3-dithiole moieties
| dc.contributor.author | I. Yavari, | en |
| dc.contributor.author | R. Hosseinpour, | en |
| dc.contributor.author | S. Skoulika | en |
| dc.date.accessioned | 2015-11-24T16:42:34Z | |
| dc.date.available | 2015-11-24T16:42:34Z | |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8568 | |
| dc.rights | Default Licence | - |
| dc.subject | Polarized olefins | en |
| dc.subject | Keteneimine | en |
| dc.subject | Dithiole | en |
| dc.subject | Dihydrothiazole | en |
| dc.title | Nef-isocyanide-Perkow synthesis of new polarized olefins containing 2- dicyanomethylene-2,3-dihydrothiazole and 2-dicyanomethylene-1,3-dithiole moieties | en |
| heal.abstract | Imidoyl chlorides (generated from isocyanides and acyl chlorides) reacts with triisopropyl phosphite, in a Perkow-type reaction, to produce 1-alkoxycarbonyl-2-(alkylimino)vinyl diisopropyl phosphate, which undergo a smooth reaction with bidentate nucleophilic intermediates obtained from the reaction between malononitrile and heterocumulenes, such as arylisothiocyanates or carbon disulfide to produce polarized olefins containing 2-dicyanomethylene-2,3-dihydrothiazole and 2-dicyanomethylene-1,3-dithiole moieties. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | http://dx.doi.org/10.1016/j.tet.2013.01.023 | - |
| heal.identifier.secondary | http://www.sciencedirect.com/science/article/pii/S0040402013000641 | - |
| heal.journalName | Tetrahedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2013 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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