Indication of molecular oscillations during free electron transfer: reaction of butyl chloride parent ions with benzyltrimethylsilanes
| dc.contributor.author | Brede, O. | en |
| dc.contributor.author | Hermann, R. | en |
| dc.contributor.author | Naumov, S. | en |
| dc.contributor.author | Perdikomatis, G. P. | en |
| dc.contributor.author | Zarkadis, A. K. | en |
| dc.contributor.author | Siskos, M. G. | en |
| dc.date.accessioned | 2015-11-24T16:39:41Z | |
| dc.date.available | 2015-11-24T16:39:41Z | |
| dc.identifier.issn | 0009-2614 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8183 | |
| dc.rights | Default Licence | - |
| dc.subject | density-functional thermochemistry | en |
| dc.subject | cation radicals | en |
| dc.subject | charge-transfer | en |
| dc.subject | exact-exchange | en |
| dc.title | Indication of molecular oscillations during free electron transfer: reaction of butyl chloride parent ions with benzyltrimethylsilanes | en |
| heal.abstract | Molecular oscillations are accompanied with electron density fluctuations mainly of the higher occupied orbitals. This is particularly marked for rotational motions of large substituents of aromatic molecules. Hence, the extremely rapid and non-adiabatic free electron transfer from benzyltrimethylsilanes to n-butyl chloride parent radical cations affords the existence of different short-living molecular conformers. This is indicated by a characteristic pattern of transient products including metastable radical cations and fragment radicals derived from a dissociative and very unstable ionisation product. (C) 2003 Elsevier B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1016/S0009-2614(03)01011-X | - |
| heal.identifier.secondary | <Go to ISI>://000185168000016 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S000926140301011X/1-s2.0-S000926140301011X-main.pdf?_tid=e74a1d2c-356f-11e3-b35d-00000aacb360&acdnat=1381824229_3955f91d0f5280c26f1a864a47ade0cd | - |
| heal.journalName | Chemical Physics Letters | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2003 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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