TiO2 photocatalyzed degradation of diazinon in an aqueous medium

dc.contributor.authorSakkas, V. A.en
dc.contributor.authorDimou, A.en
dc.contributor.authorPitarakis, K.en
dc.contributor.authorMantis, G.en
dc.contributor.authorAlbanis, T.en
dc.date.accessioned2015-11-24T16:51:39Z
dc.date.available2015-11-24T16:51:39Z
dc.identifier.issn1610-3653-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9762
dc.rightsDefault Licence-
dc.subjectphotocatalysisen
dc.subjecttio2en
dc.subjectdegradationen
dc.subjectdiazinonen
dc.subjectsuspensionsen
dc.titleTiO2 photocatalyzed degradation of diazinon in an aqueous mediumen
heal.abstractThe photocatalytic degradation of diazinon was studied over TiO2 catalysts. The kinetics obtained demonstrated that powder titania (t(1/2) = 9.7 min) was more efficient compared to pure titania thin film catalysts (t(1/2) = 29.4 min). Mineralization of organic carbon to CO2 after 360 min of irradiation was found to be 75% while heteroatoms (P, S, N) were mineralized into phosphate, sulfate and nitrate ions, respectively. A microtox test was performed to evaluate the toxicity of solutions treated by catalysts. Illumination of diazinon in the presence of TiO2 gave rise to several intermediates that have been identified by means of solid phase extraction and gas chromatography-mass spectrometry, while a simple degradation pathway is proposed.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1007/s10311-004-0091-6-
heal.identifier.secondary<Go to ISI>://000239114300002-
heal.identifier.secondaryhttp://www.springerlink.com/content/n53np474277jh556/fulltext.pdf-
heal.journalNameEnvironmental Chemistry Lettersen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2005-
heal.publisherSpringer-Verlagen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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