Synthesis of beta,gamma-unsaturated primary amides from alpha,beta-unsaturated acids and investigation of the mechanism
| dc.contributor.author | Theodorou, V. | en |
| dc.contributor.author | Gogou, M. | en |
| dc.contributor.author | Philippidou, M. | en |
| dc.contributor.author | Ragoussis, V. | en |
| dc.contributor.author | Paraskevopoulos, G. | en |
| dc.contributor.author | Skobridis, K. | en |
| dc.date.accessioned | 2015-11-24T16:49:15Z | |
| dc.date.available | 2015-11-24T16:49:15Z | |
| dc.identifier.issn | 0040-4020 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9453 | |
| dc.rights | Default Licence | - |
| dc.subject | beta,gamma-unsaturated n-tritylamides | en |
| dc.subject | beta,gamma-unsaturated primary amides | en |
| dc.subject | 3-alkenamides | en |
| dc.subject | isomerization | en |
| dc.subject | detritylation | en |
| dc.subject | base-induced rearrangement | en |
| dc.subject | unsaturated amides | en |
| dc.subject | stereoselective syntheses | en |
| dc.subject | delta-lactams | en |
| dc.subject | gamma-lactams | en |
| dc.subject | palladium | en |
| dc.subject | esters | en |
| dc.subject | 3-alkenamides | en |
| dc.subject | tritylamine | en |
| dc.subject | 4-alkenyl-2-azetidinones | en |
| dc.title | Synthesis of beta,gamma-unsaturated primary amides from alpha,beta-unsaturated acids and investigation of the mechanism | en |
| heal.abstract | alpha,beta-Unsaturated acids, through their acid chlorides, react with tritylamine in the presence of triethylamine under mild conditions, to afford in high yield and high regioselectivity the corresponding beta,gamma-unsaturated tritylamides. Detritylation with TFA generates quantitatively beta,gamma-unsaturated primary amides. An investigation of this deconjugative isomerization was performed. (C) 2011 Elsevier Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.tet.2011.05.096 | - |
| heal.identifier.secondary | <Go to ISI>://000293109400015 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0040402011007861/1-s2.0-S0040402011007861-main.pdf?_tid=c701e476-3a30-11e3-95c8-00000aacb35d&acdnat=1382346872_6eb56bad3417bf94a538dcadb85b8af6 | - |
| heal.journalName | Tetrahedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2011 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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