Ionizing radiation-induced detects in smectite clays

dc.contributor.authorGournis, D.en
dc.contributor.authorMantaka-Marketou, A. E.en
dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorPetridis, D.en
dc.date.accessioned2015-11-24T17:35:17Z
dc.date.available2015-11-24T17:35:17Z
dc.identifier.issn0342-1791-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14105
dc.rightsDefault Licence-
dc.subjectgamma irradiationen
dc.subjectsmectite claysen
dc.subjectradiation-induced defectsen
dc.subjectepren
dc.subjectinfrared reflectanceen
dc.subjectelectron-spin-resonanceen
dc.subjectparamagnetic defectsen
dc.subjectinfrared reflectanceen
dc.subjectnatural kaolinitesen
dc.subjectmontmorillonitesen
dc.subjectspectroscopyen
dc.subjectirradiationen
dc.subjectstabilityen
dc.titleIonizing radiation-induced detects in smectite claysen
heal.abstractThe interaction of gamma -rays with smectites induces paramagnetic defects in the structure of these clay minerals. The EPR spectra of three different smectites detect the creation of structural defects and trapping of organic free radicals in the clay structure upon irradiation. The defects are assigned to positive holes or trapped electrons stabilised by existing local charge imbalances in the mineral lattice. The organic radicals are derived from organic compounds present as impurities in the crystal lattice of the clay minerals. In addition, gamma -rays cause migration of small interlayer cations (such as Li+) into the layers, as clearly evidenced by EPR and FT-IR reflectance spectroscopies.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1007/s002690100153-
heal.identifier.secondary<Go to ISI>://000169213000009-
heal.journalNamePhysics and Chemistry of Mineralsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2001-
heal.publisherSpringer-Verlagen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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