Study of chlorothalonil photodegradation in natural waters and in the presence of humic substances

dc.contributor.authorSakkas, V. A.en
dc.contributor.authorLambropoulou, D. A.en
dc.contributor.authorAlbanis, T. A.en
dc.date.accessioned2015-11-24T16:48:30Z
dc.date.available2015-11-24T16:48:30Z
dc.identifier.issn0045-6535-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9332
dc.rightsDefault Licence-
dc.subjectbiocideen
dc.subjectfateen
dc.subjectdissolved organic matteren
dc.subjectenvironmenten
dc.subjectdegradationen
dc.subjectherbicidesen
dc.subjectbiocidesen
dc.subjectsoilen
dc.subjectfateen
dc.titleStudy of chlorothalonil photodegradation in natural waters and in the presence of humic substancesen
heal.abstractPhotodegradation of chlorothalonil was studied in different natural waters (sea, river and lake) as well as in distilled water under natural and simulated solar irradiation. The effect of dissolved organic matter (DOM) such as humic and fulvic substances on the photodegradation rate of chlorothalonil was also studied in simulated sunlight. The presence of DOM enhanced the photodegradation of chlorothalonil with the exception of seawater. The kinetics were determined through gas chromatography electron capture detection (GC/ECD) and the photodegradation proceeds via pseudo-first-order reaction in all cases. Half-life ranged from I to 48 h. In natural and humic water chlorothalonil photodegradation gave rise to two different intermediates compared to distilled water demonstrating that the transformation of chlorothalonil depend on the constitution of the irradiated media and especially from DOM. The byproducts identified by GC/MS techniques were: chloro-1,3-dicyanobenzene, dichloro-1,3-dicyanobenzene, trichloro-1,3-dicyanobenzene and benzamide. (C) 2002 Elsevier Science Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://000177462200006-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0045653502001212/1-s2.0-S0045653502001212-main.pdf?_tid=e8de899d32499dc6c16c3e42bb9c30c2&acdnat=1333023401_51c871dcd8b51bf589ca642e40b9ead6-
heal.journalNameChemosphereen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2002-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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