Synthesis and Characterization of Vanadium(Iii) and Oxovanadium(Iv/V) Species with Deprotonated Amide Ligands
| dc.contributor.author | Kabanos, T. A. | en |
| dc.contributor.author | Keramidas, A. D. | en |
| dc.contributor.author | Papaioannou, A. B. | en |
| dc.contributor.author | Terzis, A. | en |
| dc.date.accessioned | 2015-11-24T16:49:01Z | |
| dc.date.available | 2015-11-24T16:49:01Z | |
| dc.identifier.issn | 0022-4936 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9412 | |
| dc.rights | Default Licence | - |
| dc.title | Synthesis and Characterization of Vanadium(Iii) and Oxovanadium(Iv/V) Species with Deprotonated Amide Ligands | en |
| heal.abstract | Reaction of the amide ligand N-[2-(2-pyridylmethyleneamino)phenyl]pyridine-2-carboxamide (Hcapca) with VCl3 affords the compound trans-[VCl2(capca)] 1, the first example of a vanadium(III) complex containing a vanadium-deprotonated amide nitrogen bond, while reaction of bis(pentane-2,4-dionato)oxovanadium(IV) with the related ligands 1,2-bis(2-hydroxybenzamido)benzene (H-4hybeb) and 1-(2-hydroxybenzamido)-2-(2-pyridinecarboxamido)benzene (H-3hypyb) yields the complexes Na2[VIVO(hybeb)] 2 and Na[VIVO(hypyb)] 3 respectively; the X-ray crystal structures of 1 and 3 are reported. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1993KW99900032 | - |
| heal.journalName | Journal of the Chemical Society-Chemical Communications | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1993 | - |
| heal.publisher | Royal Society of Chemistry | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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