Self-assembly, molecular dynamics, and kinetics of structure formation in dipole-functionalized discotic liquid crystals
| dc.contributor.author | Elmahdy, M. M. | en |
| dc.contributor.author | Dou, X. | en |
| dc.contributor.author | Mondeshki, M. | en |
| dc.contributor.author | Floudas, G. | en |
| dc.contributor.author | Butt, H. J. | en |
| dc.contributor.author | Spiess, H. W. | en |
| dc.contributor.author | Mullen, K. | en |
| dc.date.accessioned | 2015-11-24T18:35:40Z | |
| dc.date.available | 2015-11-24T18:35:40Z | |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/17122 | |
| dc.rights | Default Licence | - |
| dc.subject | hexa-peri-hexabenzocoronenes | en |
| dc.subject | glass-transition | en |
| dc.subject | solid-state | en |
| dc.subject | dielectric-spectroscopy | en |
| dc.subject | columnar hexabenzocoronene | en |
| dc.subject | nmr-spectroscopy | en |
| dc.subject | phase-change | en |
| dc.subject | temperature | en |
| dc.subject | pressure | en |
| dc.subject | crystallization | en |
| dc.title | Self-assembly, molecular dynamics, and kinetics of structure formation in dipole-functionalized discotic liquid crystals | en |
| heal.abstract | The self-assembly, the molecular dynamics, and the kinetics of structure formation are studied in dipole-functionalized hexabenzocoronene (HBC) derivatives. Dipole substitution destabilizes the columnar crystalline phase except for the dimethoxy- and monoethynyl-substituted HBCs that undergo a reversible transformation to the crystalline phase. The disk dynamics are studied by dielectric spectroscopy and site-specific NMR techniques that provide both the time-scale and geometry of motion. Application of pressure results in the thermodynamic phase diagram that shows increasing stability of the crystalline phase at elevated pressures. Long-lived metastability was found during the transformation between the two phases. These results suggest new thermodynamic and kinetic pathways that favor the phase with the highest charge carrier mobility. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Ja7113618 | - |
| heal.identifier.secondary | <Go to ISI>://000254933000056 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ja7113618 | - |
| heal.journalName | J Am Chem Soc | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2008 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: