Preparation of 2-picolylarsonic acid and its reductive cleavage by ascorbic acid/iodine and by thiophenol
| dc.contributor.author | Ioannou, P. V. | en |
| dc.contributor.author | Afroudakis, P. A. | en |
| dc.contributor.author | Siskos, M. G. | en |
| dc.date.accessioned | 2015-11-24T16:45:24Z | |
| dc.date.available | 2015-11-24T16:45:24Z | |
| dc.identifier.issn | 1042-6507 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8925 | |
| dc.rights | Default Licence | - |
| dc.subject | 2-picolyl chloride | en |
| dc.subject | arsonic acids | en |
| dc.subject | ascorbic acid | en |
| dc.subject | dialkylaminoethyl halides | en |
| dc.subject | picolylarsonic acid | en |
| dc.subject | the meyer reaction | en |
| dc.subject | thiophenol | en |
| dc.subject | arsonic acids | en |
| dc.subject | arsonolipids | en |
| dc.subject | analogs | en |
| dc.subject | phospholipids | en |
| dc.subject | arsenic(iii) | en |
| dc.subject | inhibition | en |
| dc.subject | thiols | en |
| dc.title | Preparation of 2-picolylarsonic acid and its reductive cleavage by ascorbic acid/iodine and by thiophenol | en |
| heal.abstract | Contrary to dialkylaminoethyl halides, 2-picolyl chloride reacts with alkaline arsenite to give nearly quantitative yields 2-picolylarsonic acid. This acid is decomposed by ascorbic acid in the presence of catalytic amounts of iodine to 2-picoline and arsenious acid, most likely by hydride transfer from the ascorbic acid. Thiophenol decomposes this arsonic acid very quickly to 2-picoline, diphenyl disulfide and triphenyl trithioarsenite. In this case a proton from the thiophenol is transferred to the incipient 2-picolyl carbanion. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1080/10426500270146767 | - |
| heal.identifier.secondary | <Go to ISI>://000180281300004 | - |
| heal.identifier.secondary | http://www.tandfonline.com/doi/pdf/10.1080/10426500214875 | - |
| heal.journalName | Phosphorus Sulfur and Silicon and the Related Elements | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2002 | - |
| heal.publisher | Taylor & Francis | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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