Metal complexes of the Schiff base ligand L=1,2-bis(2 '-pyridylmethyleneimino)benzene with Ni2+, Fe2+ and Cu2+ and their reactions with bridged bidentate ligands. The crystal structure of the complex [NiL(H2O)(2)]Cl-2
| dc.contributor.author | Garoufis, A. | en |
| dc.contributor.author | Kasselouri, S. | en |
| dc.contributor.author | Mitsopoulou, C. A. | en |
| dc.contributor.author | Sletten, J. | en |
| dc.contributor.author | Papadimitriou, C. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.date.accessioned | 2015-11-24T16:41:32Z | |
| dc.date.available | 2015-11-24T16:41:32Z | |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8434 | |
| dc.rights | Default Licence | - |
| dc.subject | schiff base ligand | en |
| dc.subject | tetradentate ligand | en |
| dc.subject | ni(ii) complexes | en |
| dc.subject | crystal structure | en |
| dc.subject | one-dimensional conductors | en |
| dc.subject | amide bond | en |
| dc.subject | pyrazine | en |
| dc.subject | iron | en |
| dc.subject | monohydrate | en |
| dc.subject | adducts | en |
| dc.subject | cobalt | en |
| dc.title | Metal complexes of the Schiff base ligand L=1,2-bis(2 '-pyridylmethyleneimino)benzene with Ni2+, Fe2+ and Cu2+ and their reactions with bridged bidentate ligands. The crystal structure of the complex [NiL(H2O)(2)]Cl-2 | en |
| heal.abstract | The preparation and the characterization of Ni2+ and Fe2+ complexes of the neutral, N-4(-) non-macrocyclic Shiff base ligand, L = 1,2-bis-(2'-pyridylmethyleneimino)benzene of formulae FeLCl2 and [NiL(H2O)(2)]Cl-2(-) are reported. The structure of the Ni complex, [NiL(H2O)(2)]Cl-2, has been determined by X-ray diffraction methods. The nickel atom has a six coordinate NiN4O2 chromophore with distorted octahedral coordination. The ligand L acts as tetradentate chelate, with the ligated atoms in an essentially planar arrangement around the metal with the remaining-axial coordination sites occupied by water ligands. In addition a series of ligand-bridged LMCl2 oligomeric complexes of the type {[LME]Cl-2}(n) (M = Ni, Fe, Cu and E = pyrazine, 4,4'-bipyridine, 1,4-dicyanobenzene, 1,4-cyanopyridine), have been synthesized and characterized by elemental analysis, solid state conductivity, magnetic susceptibility measurements and IR, UV-VIS and ES-MS spectroscopic techniques. Doping of these complexes with iodine exhibited conductivities in the solid state comparable to similar dimethylglyoxime derivative complexes. (C) 1998 Elsevier Science Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000078033400006 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538798002654/1-s2.0-S0277538798002654-main.pdf?_tid=6e3c5cf589a8cc5a2e09d2388e7c00c1&acdnat=1333029196_a49d18f00b3305d25943abeb7797f6cb | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1999 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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