The reaction of glutamic acid and trinitrobenzenesulfonic acid-kinetic study and analytical application

dc.contributor.authorKiranas, E. R.en
dc.contributor.authorTzouwaraKarayanni, S. M.en
dc.contributor.authorKarayannis, M. I.en
dc.date.accessioned2015-11-24T16:51:04Z
dc.date.available2015-11-24T16:51:04Z
dc.identifier.issn0039-9140-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9684
dc.rightsDefault Licence-
dc.subjectglutamic aciden
dc.subjectkinetic studyen
dc.subjectkinetic determinationen
dc.subjecttrinitrobenzenesulfonic aciden
dc.subjectelectrodeen
dc.titleThe reaction of glutamic acid and trinitrobenzenesulfonic acid-kinetic study and analytical applicationen
heal.abstractSome kinetic aspects of the reaction of glutamic acid (GLU) and Trinitrobenzenesulfonic acid (TNBS) were studied spectrophotometrically (420 nm), under pseudo-first order reaction conditions. The effect of GLU, TNBS: SO32- and H+ had been investigated. Working curves for the initial rates IR versus [GLU] are linear in the range 7.5-30.0 mM. The regression equation is IR = (8 +/- 8)E-6+(39 +/- 0.5).[GLU] and the correlation coefficient r = 0.9998. The limit of quantitation is 1.5 mu M GLU and the relative standard deviation of the method 1.2%. The kinetics of the interfering TNBS hydrolysis reaction in alkaline range of pH, as well as the effect of sulfite concentration on the main reaction, are also presented. The analytical application of the reaction for the kinetic spectrophotometric assay of GLU and other aminoacids, as well as TNBS, is presented and the relevant advantages and disadvantages of the method are discussed. (C) 1997 Elsevier Science B.V.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://A1997XC19500020-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0039914096022059/1-s2.0-S0039914096022059-main.pdf?_tid=de279c6b4610a16f4050a1744d107f20&acdnat=1335370618_e6a674a2116842d856e2cbe11eddd1a3-
heal.journalNameTalantaen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1997-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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