Tele vs. oxidative substitution of hydrogen in meta monochloromethyl, dichloromethyl, and trichloromethyl nitrobenzenes in the reaction with Grignard reagents

dc.contributor.authorMakosza, M.en
dc.contributor.authorVarvounis, G.en
dc.contributor.authorSurowiec, M.en
dc.contributor.authorGiannopoulo, T.en
dc.date.accessioned2015-11-24T16:50:02Z
dc.date.available2015-11-24T16:50:02Z
dc.identifier.issn1434-193X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9560
dc.rightsDefault Licence-
dc.subjectgrignard reagentsen
dc.subjectnitroarenesen
dc.subjectoxidative substitutionen
dc.subjectvicarious nucleophilic-substitutionen
dc.subjectaromatic nitro-compoundsen
dc.subjectsilyl enol ethersen
dc.subjectconjugate additionen
dc.subjectfacile synthesisen
dc.subjectnitroarenesen
dc.subjectalkylationen
dc.subjectmechanismen
dc.subjectadductsen
dc.subjectsystemen
dc.titleTele vs. oxidative substitution of hydrogen in meta monochloromethyl, dichloromethyl, and trichloromethyl nitrobenzenes in the reaction with Grignard reagentsen
heal.abstractGrignard reagents add to nitrobenzene derivatives containing trichloromethyl, dichloromethyl, and monochloromethyl groups in the meta position to form sigma(H) adducts, which are either further converted through departure of a chloride anion, giving products of tele substitution, or oxidized to products of oxidative nucleophilic substitution of hydrogen. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1002/ejoc.200300223-
heal.identifier.secondary<Go to ISI>://000185734000012-
heal.identifier.secondaryhttp://onlinelibrary.wiley.com/store/10.1002/ejoc.200300223/asset/3791_ftp.pdf?v=1&t=hmrggtus&s=127b512fff1d5042c7989723d0bed55a1ddcac12-
heal.journalNameEuropean Journal of Organic Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2003-
heal.publisherWiley-VCH Verlagen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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