Preparation and spectral studies of dinuclearmixed-ligand copper(I) complexes. The crystal structure of bis[ΞΌ-S(Pyridine-2-Thione)(tmtp) Copper(I)Bromide]
| dc.contributor.author | Aslanidis, P. | en |
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.contributor.author | Karagiannidis, P. | en |
| dc.contributor.author | Kojic-Prodic, B. | en |
| dc.contributor.author | Luic, M. | en |
| dc.date.accessioned | 2015-11-24T16:45:23Z | |
| dc.date.available | 2015-11-24T16:45:23Z | |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8923 | |
| dc.rights | Default Licence | - |
| dc.title | Preparation and spectral studies of dinuclearmixed-ligand copper(I) complexes. The crystal structure of bis[ΞΌ-S(Pyridine-2-Thione)(tmtp) Copper(I)Bromide] | en |
| heal.abstract | [Cu(tmtp)Br]n (tmtp = tri-m-tolylphosphine) reacts with heterocyclic thiones (L) [L = pyridine-2-thione (py2SH), 1,3-thiazolidine-2-thione (tzdtH), benz-1,3-imidazoline-2-thione (bzimtH2), benz-1,3-thiazoline-2-thione (bztzdtH), imidazoline-2-thione (imtH), benz-1,3-oxazoline-2-thione (bzoxtH2), 5-nitrobenz-1,3-imidazoline-2-thione (nbzimtH2), and 5-methyl-benz-1,3-imidazoline-2-thione (mebzimtH2)] to give binuclear complexes of the general formula [Cu(tmtp)(L)Br]2. These complexes have been characterized by various spectroscopic methods. The crystal structure of the pyridine-2-thione complex has been determined by single-crystal X-ray diffraction methods. The molecule contains a planar Cu2S2 moiety with Cuξ—ΈS bond lengths of 2.3348(9) and 2.4879(7) Γ…. The Cuξ—ΈBr and Cuξ—ΈP distances are 2.4929(1) and 2.2525(4) Γ…, respectively, whereas the Cuβ‹―Cu separation is 2.6906(1) Γ…. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | http://www.sciencedirect.com/science/article/pii/S0277538700836803 | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1994 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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