Synthesis, solution and spectral studies of palladium(II) complexes with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone. Crystal structure of a tripalladium complex
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Yadav, P. N.
Demertzis, M. A.
Kovala-Demertzi, D.
Castineiras, A.
West, D. X.
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peer reviewed
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Inorganica Chimica Acta
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The reactions of palladium(II) salts with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone, H(2)Ap3Pr, are described. The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion, Ap3Pr(2-), are reported. The X-ray crystal structure determination of [Pd(Ap3Pr(2))](3).DMF shows it to contain a chair-form hexagon of alternating Pd and S atoms to form a molecular bowl. The spectrophotometric characterization of H(2)Ap3Pr is also reported. (C) 2002 Elsevier Science B.V. All rights reserved.
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trinuclear triangulo palladium (ii), 2-hydroxyacetophenone n(3) propylthiosemicarbazone, one-dimensional extended network, crystal structures, dissociation constants, first organotin complex, n-4-substituted thiosemicarbazones, copper(ii) complexes, antitumor-activity, in-vitro, hydrogen, platinum(ii), adducts
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<Go to ISI>://000175344600031
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en
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Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας