Silver(I) complexes with heterocyclic thiones and tertiary phosphines as ligands. Part 4. Dinuclear complexes of silver(I) bromide: the crystal structure of bis[bromo-(pyrimidine-2-thione)(triphenylphosphine)silver(I)]
| dc.contributor.author | Cox, P. J. | en |
| dc.contributor.author | Aslanidis, P. | en |
| dc.contributor.author | Karagiannidis, P. | en |
| dc.contributor.author | Hadjikakou, S. | en |
| dc.date.accessioned | 2015-11-24T16:47:17Z | |
| dc.date.available | 2015-11-24T16:47:17Z | |
| dc.identifier.issn | 0020-1693 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9161 | |
| dc.rights | Default Licence | - |
| dc.subject | crystal structures | en |
| dc.subject | heterocyclic thione complexes | en |
| dc.subject | photolysis | en |
| dc.subject | silver(i) bromide complexes | en |
| dc.subject | triphenylphosphine complexes | en |
| dc.subject | copper(i) bromide | en |
| dc.subject | cu(i) complexes | en |
| dc.subject | mononuclear | en |
| dc.subject | triphenylphosphine | en |
| dc.title | Silver(I) complexes with heterocyclic thiones and tertiary phosphines as ligands. Part 4. Dinuclear complexes of silver(I) bromide: the crystal structure of bis[bromo-(pyrimidine-2-thione)(triphenylphosphine)silver(I)] | en |
| heal.abstract | Mixed-ligand complexes of the formula [Ag(PPh3)(L)Br](2) were obtained by treatment of various heterocyclic thiones L (L = pyridine-2-thione (py2SH), pyrimidine-2-thione (pymtH), bent-1,3-imidazoline-2-thione (bzimtH(2)), benz-1,3-thiazoline-2-thione (bztztH). 1-methyl-1,3-imidazoline-2-thione (meimtH) and 5-methoxy-benz-1,3-imidazoline-2-thione (5MeObzimtH(2))) with equivalent quantities of silver(I) bromide and triphenylphosphine in dry acetone. The compounds were characterized by their IR, far-IR, UV-Vis and H-1 NMR spectroscopic data. The crystal structure of [Ag(PPh3)(pymtH)Br](2) was determined by single-crystal X-ray diffraction methods. The complex exhibits a planar Ag2Br2 moiety in which each of the doubly bromine-bridged Ag(I) centres is further bonded to one phosphine P and one thione S atom. (C) 2000 Elsevier Science B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | 10.1016/S0020-1693(00)00286-3 | - |
| heal.identifier.secondary | <Go to ISI>://000166250900023 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0020169300002863/1-s2.0-S0020169300002863-main.pdf?_tid=7fbbbed56a3dc4d82b55bb330f6e4146&acdnat=1333030103_e2eacadf42ab093500d41e6018cf77b1 | - |
| heal.journalName | Inorganica Chimica Acta | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2000 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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