Functionalization of niobium electrodes for the construction of impedimetric biosensors

dc.contributor.authorHelali, S.en
dc.contributor.authorAbdelghani, A.en
dc.contributor.authorHafaiedh, I.en
dc.contributor.authorMartelet, C.en
dc.contributor.authorProdromidis, M. I.en
dc.contributor.authorAlbanis, I.en
dc.contributor.authorJaffrezic-Renault, N.en
dc.date.accessioned2015-11-24T16:38:16Z
dc.date.available2015-11-24T16:38:16Z
dc.identifier.issn0928-4931-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8023
dc.rightsDefault Licence-
dc.subjectatrazineen
dc.subjectniobium electrodeen
dc.subjectanodic niobiurn oxideen
dc.subjectelectrochemical impedance spectroscopyen
dc.subjectbiosensorsen
dc.subjectelectrochemical impedance spectroscopyen
dc.subjectimmunosensoren
dc.subjectimmobilizationen
dc.subjectgolden
dc.subjectmonolayeren
dc.subjectcatalystsen
dc.subjectsensoren
dc.titleFunctionalization of niobium electrodes for the construction of impedimetric biosensorsen
heal.abstractThis paper describes the development of an impedimetric immunosensor, based on niobium/niobium oxide (Nb[NbOxHy) electrodes, for the detection of atrazine. Niobium oxide was anodically formed onto niobium electrodes at 25 V in 1 M H2SO4. Hydrous oxide layers were then silanized with APTES, and using glutaraldehyde as a cross linker, Fab fragment k47 antibody was covalently immobilized onto the surface of the electrodes. Electrochemical impedance spectroscopy (EIS) was used to characterize the building-up of the immunosensors as well as the binding of atrazine to its specific antibody. In presence of ferricyanide redox species and under a cathodic polarization voltage (-1.2 V versus SCE), the relationship between the concentration of atrazine and the change of the electron transfer resistance value was studied. (c) 2007 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.msec.2007.10.078-
heal.identifier.secondary<Go to ISI>://000258076100046-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0928493107002032/1-s2.0-S0928493107002032-main.pdf?_tid=85278be254ad39ba70938abdd230a0cd&acdnat=1333037170_60b7c8d9a5ecf8b0abfa7cb97c26e4de-
heal.journalNameMaterials Science & Engineering C-Biomimetic and Supramolecular Systemsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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