Synthesis, and Structural Characterization, of Two Novel, CdIII Ξ²-diketonates [Gd4(ΞΌ3-OH)4(ΞΌ2-H2O)2(H2O)4(hfpd)8].2C6H6.H2O (1) and [Gd(hfpd)3(MeCO)(H2O)] (2) (hfpd-H: 1,1,1,5,5,5-hexafluoropentane-2,4-dione)

dc.contributor.author	J. C. Plakatouras,	en
dc.contributor.author	I. Baxter,	en
dc.contributor.author	M. B. Hursthouse,	en
dc.contributor.author	K. M. A. Malik,	en
dc.contributor.author	J. McAleese,	en
dc.contributor.author	S. R. Drake	en
dc.date.accessioned	2015-11-24T16:49:22Z
dc.date.available	2015-11-24T16:49:22Z
dc.identifier.uri	https://olympias.lib.uoi.gr/jspui/handle/123456789/9475
dc.rights	Default Licence	-
dc.title	Synthesis, and Structural Characterization, of Two Novel, CdIII Ξ²-diketonates [Gd4(ΞΌ3-OH)4(ΞΌ2-H2O)2(H2O)4(hfpd)8].2C6H6.H2O (1) and [Gd(hfpd)3(MeCO)(H2O)] (2) (hfpd-H: 1,1,1,5,5,5-hexafluoropentane-2,4-dione)	en
heal.abstract	Two novel Gdlll-hfpd complexes 1 and 2 have been synthesised from aqueous and non-aqueous media; the crystal structural studies reveal that 1 has a M406 bicapped cubane core with the metals having tricapped trigonal prismatic geometry, while 2 is a monomeric adduct with water and acetone in the coordination sphere, with the metal having square antiprismatic geometry.	en
heal.access	campus	-
heal.fullTextAvailability	TRUE	-
heal.journalName	J. Chem. Soc., Chem. Commun.	en
heal.journalType	peer reviewed	-
heal.language	en	-
heal.publicationDate	1994	-
heal.recordProvider	Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας	el
heal.type	journalArticle	-
heal.type.el	Άρθρο Περιοδικού	el
heal.type.en	Journal article	en

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