Carbonyl sulfide insertion reactions into metal-alkoxide bonds. Synthesis and molecular structure of di[bis(methylthiocarbonato)tris (methanol)calcium]

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dc.contributor.authorV. -C. Arunasalam,en
dc.contributor.authorD. M. P. Mingos,en
dc.contributor.authorJ. C. Plakatouras,en
dc.contributor.authorI. Baxter,en
dc.contributor.authorM. B. Hursthouse,en
dc.contributor.authorK. M. A. Maliken
dc.date.accessioned2015-11-24T16:53:24Z
dc.date.available2015-11-24T16:53:24Z
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10010
dc.rightsDefault Licence-
dc.titleCarbonyl sulfide insertion reactions into metal-alkoxide bonds. Synthesis and molecular structure of di[bis(methylthiocarbonato)tris (methanol)calcium]en
heal.abstractThe reaction of COS gas with a suspension of [M(OMe)2]Ξ· (M = Mg and Ca) in methanol yields the insertion compounds, [M(OCSOMe)2(MeOH)x]Ξ· (M = Mg 1, View the MathML source) in high yield; the magnesium compound is polymeric, whilst X-ray crystallography reveals that the calcium complex 2 is a centrosymmetric dimer with eight coordinated calcium(II) ions and two distinct methylthiocarbonato (MTC) ligand coordinations modes, the structural framework being stabilised by an extensive network of hydrogen bonding.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondaryhttp://www.sciencedirect.com/science/article/pii/027753879500034P-
heal.journalNamePolyhedronen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1995-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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