Synthesis, Characterization and Electronic Properties of trans-[4-(Alkoxycarbonyl)phenyl]porphyrin-[Ru-II(bpy)(3)](2) Complexes or Boron-Dipyrrin Conjugates as Panchromatic Sensitizers for DSSCs

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dc.contributor.authorStangel, C.en
dc.contributor.authorLadomenou, K.en
dc.contributor.authorCharalambidis, G.en
dc.contributor.authorPanda, M. K.en
dc.contributor.authorLazarides, T.en
dc.contributor.authorCoutsolelos, A. G.en
dc.date.accessioned2015-11-24T16:49:28Z
dc.date.available2015-11-24T16:49:28Z
dc.identifier.issn1434-1948-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9490
dc.rightsDefault Licence-
dc.subjectenergy transferen
dc.subjectsolar cellsen
dc.subjectsensitizersen
dc.subjectdyesen
dc.subjectpigmentsen
dc.subjectporphyrinoidsen
dc.subjectrutheniumen
dc.subjectboronen
dc.subjectnanocrystalline tio2 electrodesen
dc.subjectefficient co-sensitizationen
dc.subjectsolar-cellsen
dc.subjectruthenium sensitizersen
dc.subjectenergy-transferen
dc.subjectphotoelectrochemical propertiesen
dc.subjectconversion-efficiencyen
dc.subjectquantum yieldsen
dc.subjectexcited-stateen
dc.subjectorganic-dyesen
dc.titleSynthesis, Characterization and Electronic Properties of trans-[4-(Alkoxycarbonyl)phenyl]porphyrin-[Ru-II(bpy)(3)](2) Complexes or Boron-Dipyrrin Conjugates as Panchromatic Sensitizers for DSSCsen
heal.abstractTwo porphyrin-based dyes were synthesized that incorporate two additional chromophores to absorb in a wider UV/Vis region. In the first dye, a porphyrin ring is linked through an amide bond to two [Ru(bpy)(3)](2+) units, forming a symmetric [Ru(bpy)(3)]-porphyrin-[Ru(bpy)(3)] {Por(COOH)(2)[Ru(bpy)(3)](2)} system. The second porphyrin is trans substituted through a triple bond to the meso position with two boron dipyrrin (BDP) molecules {Por(COOH)(2)(BDP)(2)}. Both porphyrins bear two carboxylic groups capable of binding onto a TiO2 surface, with potential applications in dye-sensitized solar cells (DSSCs). The title dyes were characterized by means of H-1 and C-13 NMR spectroscopy, elemental analysis, MALDI-TOF, UV/Vis absorption and emission studies.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1002/ejic.201201248-
heal.identifier.secondary<Go to ISI>://000316395600005-
heal.identifier.secondaryhttp://onlinelibrary.wiley.com/store/10.1002/ejic.201201248/asset/1275_ftp.pdf?v=1&t=hmri99fy&s=1691899cde6d48593d1d1f1b07f16b2badce2a7c-
heal.journalNameEuropean Journal of Inorganic Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2013-
heal.publisherWiley-VCH Verlagen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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