Application of a novel chemometric approach to the determination of aqueous photolysis rates of organic compounds in natural waters
| dc.contributor.author | Giokas, D. L. | en |
| dc.contributor.author | Vlessidis, A. G. | en |
| dc.date.accessioned | 2015-11-24T16:52:29Z | |
| dc.date.available | 2015-11-24T16:52:29Z | |
| dc.identifier.issn | 0039-9140 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9893 | |
| dc.rights | Default Licence | - |
| dc.subject | chemometrics | en |
| dc.subject | multivariate optimization | en |
| dc.subject | natural waters | en |
| dc.subject | photodegradation | en |
| dc.subject | sunscreen agents | en |
| dc.subject | hydroxyl radicals | en |
| dc.subject | pesticides | en |
| dc.subject | kinetics | en |
| dc.subject | matter | en |
| dc.subject | bicarbonate | en |
| dc.subject | degradation | en |
| dc.subject | nitrate | en |
| dc.title | Application of a novel chemometric approach to the determination of aqueous photolysis rates of organic compounds in natural waters | en |
| heal.abstract | The utility of multivariate optimization methods in the determination of aqueous photolysis rates of organic compounds is examined in this study. A basic pursue was to designate the appropriate experimental design plan that extend the analytical utility of multivariate methods from qualitative data interpretation approaches, as applied thus far, to quantitative estimation methods. A three-level second-order central composite design with parameter concentrations (factor levels) beyond the environmental realistic concentrations was employed for that purpose enabling statistically significant effects to be determined. Method application is demonstrated in the first photodegradation study of two UV absorbing chemicals in natural waters. The results suggest that the proposed approach of enables a good approximation of the real behavior in terms of both qualitative and quantitative data interpretation with minimal loss of information. (c) 2006 Elsevier B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.talanta.2006.03.060 | - |
| heal.identifier.secondary | <Go to ISI>://000244059600044 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S003991400600258X/1-s2.0-S003991400600258X-main.pdf?_tid=da057990-356a-11e3-877b-00000aab0f26&acdnat=1381822059_2bec6300049b44702c021507f7955cc0 | - |
| heal.journalName | Talanta | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2007 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Files
License bundle
1 - 1 of 1
Loading...
- Name:
- license.txt
- Size:
- 1.74 KB
- Format:
- Item-specific license agreed upon to submission
- Description: