Preparation and characterization of the seven coordinate cadmium(II) complex [Cd(3,4-H(2)dhb)(2)(H2O)3]center dot HCl center dot(3,4-H(3)dhb)center dot 2.5H(2)O; The first structural determination of a complex containing the 3,4-dihydroxybenzoato(-1)(3,4-H(2)dhb(-)) ligand

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dc.contributor.authorAletras, V.en
dc.contributor.authorHadjiliadis, N.en
dc.contributor.authorStabaki, D.en
dc.contributor.authorKaraliota, A.en
dc.contributor.authorKamariotaki, M.en
dc.contributor.authorButler, I.en
dc.contributor.authorPlakatouras, J. C.en
dc.contributor.authorPerlepes, S.en
dc.date.accessioned2015-11-24T16:45:21Z
dc.date.available2015-11-24T16:45:21Z
dc.identifier.issn0277-5387-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8918
dc.rightsDefault Licence-
dc.subjectcd-ii complexen
dc.subjectseven-coordinate complexen
dc.subjectcd-113 nmren
dc.subject3,4-dihydroxybenzoato(-1) cd-ii complexen
dc.subjectcrystal structureen
dc.subject3,4-dihydroxybenzoic aciden
dc.subjectoxovanadium(iv) complexesen
dc.subjectdihydroxybenzoic acidsen
dc.subjectcrystal-structureen
dc.subjectmetal-ionsen
dc.subjectzinc(ii)en
dc.subjectderivativesen
dc.subjectcopper(ii)en
dc.subjectbehavioren
dc.subjectbindingen
dc.titlePreparation and characterization of the seven coordinate cadmium(II) complex [Cd(3,4-H(2)dhb)(2)(H2O)3]center dot HCl center dot(3,4-H(3)dhb)center dot 2.5H(2)O; The first structural determination of a complex containing the 3,4-dihydroxybenzoato(-1)(3,4-H(2)dhb(-)) liganden
heal.abstractThe 1:2:1 reaction of CdCl2 . 2.5H(2)O with 3,4-dihydroxybenzoic acid (3,4-H(3)dhb) and KOH in (PrOH)-O-n-H2O gave the unique, seven-coordinate cadmium(II) complex [Cd(3,4-H(2)dhb)(2)(H2O)(3)]. HCl .(3,4-H(3)dhb). 2.5H(2)O as one of the products. Crystal structure and Cd-13 NMR studies showed that 3.4-H(2)dhb(-) behaves as a bidentate chelate with ligated atoms being the carboxylate oxygens, but that seven-coordination is not retained in aqueous solution. Copyright (C) 1997 Elsevier Science Ltd.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://A1997WK20200020-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0277538796004020/1-s2.0-S0277538796004020-main.pdf?_tid=7d9ab1d9cb7df88ed09283d3c6451b1d&acdnat=1333035831_b73b073194101f97da8598b3fc10ab75-
heal.journalNamePolyhedronen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1997-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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