Novel organotin(IV) compounds derived from bis(organostannyl)methanes: Synthesis and crystal structures of bis[diphenyl(pyridin-2-onato)stannyl]methane and bis[bromophenyl(pyrimidine-2-thionato)stannyl]methane center dot C7H8
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.contributor.author | Jurkschat, K. | en |
| dc.contributor.author | Schurmann, M. | en |
| dc.date.accessioned | 2015-11-24T16:42:54Z | |
| dc.date.available | 2015-11-24T16:42:54Z | |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8616 | |
| dc.rights | Default Licence | - |
| dc.subject | organotin compounds | en |
| dc.subject | 2-hydroxypyridine | en |
| dc.subject | pyrimidine-2-thione | en |
| dc.subject | x-ray diffraction analysis | en |
| dc.subject | heterocyclic thioamides | en |
| dc.subject | molecular-structure | en |
| dc.subject | complexes | en |
| dc.subject | tin(iv) | en |
| dc.subject | ligands | en |
| dc.subject | bis(2-pyridinethiolato)tin(ii) | en |
| dc.subject | 2-mercaptopyrimidine | en |
| dc.subject | derivatives | en |
| dc.subject | systems | en |
| dc.title | Novel organotin(IV) compounds derived from bis(organostannyl)methanes: Synthesis and crystal structures of bis[diphenyl(pyridin-2-onato)stannyl]methane and bis[bromophenyl(pyrimidine-2-thionato)stannyl]methane center dot C7H8 | en |
| heal.abstract | Reaction between bis(chlorodiphenylstanyl)methane and the sodium salt of 2-hydroxypyridine (pyONa) in the molar ratio of 1:2 provides the organotin hydroxide derivative [Ph-2(pyO)SnCH2Sn(OH)Ph-2](2) (1) (where pyO = anion of 2-hydroxypyridine), while reaction of bis(dibromophenylstanyl) methane with the sodium salt of pyrimidine-2-thione (pmtNa) in molar ratio of 1:4 gives the corresponding organotin thiolate derivative, as its toluene solvate [BrPh(pmt)Sn](2)CH(2)center dot C7H8 (2) (where pmt = anion of pyrimidine-2-thione). Both compounds were characterized by single crystal X-ray diffraction analysis and contain five-coordinate tin atoms. Compound 1 is a centrosymmetric head-to-tail dimmer with almost symmetrical Sn(1)-O(H)-Sn(2A) bridges. (c) 2005 Elsevier B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.jorganchem.2005.11.056 | - |
| heal.identifier.secondary | <Go to ISI>://000236451400027 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0022328X05010144/1-s2.0-S0022328X05010144-main.pdf?_tid=043b6f96d2714864bee715e404a39f80&acdnat=1333030170_b17b38b2dd9742829ee014b8d82f7ed1 | - |
| heal.journalName | Journal of Organometallic Chemistry | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2006 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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