Functional ization of iron oxide magnetic nanoparticles with poly(methyl methacrylate) brushes via grafting-from atom transfer radical polymerization

dc.contributor.authorGarcia, I.en
dc.contributor.authorZafeiropoulos, N. E.en
dc.contributor.authorJanke, A.en
dc.contributor.authorTercjak, A.en
dc.contributor.authorEceiza, A.en
dc.contributor.authorStamm, M.en
dc.contributor.authorMondragon, I.en
dc.date.accessioned2015-11-24T17:34:33Z
dc.date.available2015-11-24T17:34:33Z
dc.identifier.issn0887-624X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13989
dc.rightsDefault Licence-
dc.subjectatomic force microscopy (afm)en
dc.subjectatom transfer radical polymerization (atrp)en
dc.subjectft-iren
dc.subjectgraft polymerizationen
dc.subjectmagnetic nanoparticlesen
dc.subjectmethyl-methacrylateen
dc.subjectarenesulfonyl chloridesen
dc.subjectsilica nanoparticlesen
dc.subjecthybrid materialsen
dc.subjectuniversal classen
dc.subjectsurfaceen
dc.subjectpolystyreneen
dc.subjectinitiatorsen
dc.subjectparticlesen
dc.subjectdensityen
dc.titleFunctional ization of iron oxide magnetic nanoparticles with poly(methyl methacrylate) brushes via grafting-from atom transfer radical polymerizationen
heal.abstractA key problem with nanomaterials is the difficulty of controlling the dispersion of nanoparticles inside an organic medium. To overcome this problem, functionalization of the nanoparticle surface is required. Poly(methyl methacrylate) (PMMA) brushes were grown on the surface of iron oxide magnetic nanoparticles with atom transfer radical polymerization and a grafting-from approach. Modified magnetic nanoparticles with a graft density of 0.1 PMMA chains/nm(2) were obtained. Cu(II), used as a deactivating complex, allowed good control of the polymerization along with a narrow polydispersity of the polymer chains. The functionalized magnetic nanoparticles were characterized with Fourier transform infrared spectroscopy, thermogravimetric analysis, gel permeation chromatography, and atomic force microscopy. (c) 2007 Wiley Periodicals, Inc.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1002/Pola.21854-
heal.identifier.secondary<Go to ISI>://000244267700020-
heal.journalNameJournal of Polymer Science Part a-Polymer Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.publisherWileyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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