Conformational Properties of Ring Ab Diblock Copolymers

dc.contributor.authorVlahos, C.en
dc.contributor.authorHadjichristidis, N.en
dc.contributor.authorKosmas, M. K.en
dc.contributor.authorRubio, A. M.en
dc.contributor.authorFreire, J. J.en
dc.date.accessioned2015-11-24T16:54:43Z
dc.date.available2015-11-24T16:54:43Z
dc.identifier.issn0024-9297-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10187
dc.rightsDefault Licence-
dc.subjectmonte-carlo calculationen
dc.subjecthydrodynamic propertiesen
dc.subjectcyclic polymersen
dc.subjectstar polymersen
dc.subjectdimensionsen
dc.subjectgyrationen
dc.subjectradiusen
dc.titleConformational Properties of Ring Ab Diblock Copolymersen
heal.abstractRing diblock copolymers with different lengths of the A and B blocks have been investigated using theoretical and numerical simulation methods. The theoretical calculations are based on a first-order expansion in the parameter epsilon = 4 - d and extend to chains in a common Theta solvent, in a common good solvent, and in selective solvents, though only the first case is discussed in detail. The Monte Carlo calculations are performed for a common Theta solvent case with an off-lattice model of Gaussian units which interact through a Lennard-Jones potential. Averaged dimensions for each of the blocks and for the whole chain are obtained, and the theoretical and simulation results are analyzed and discussed. From the results, we have obtained general trends for all these different properties, and the most important differences and similarities with linear or homopolymer chains have been identified.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ma00124a021-
heal.identifier.secondary<Go to ISI>://A1995RX35700021-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdf/10.1021/ma00124a021-
heal.journalNameMacromoleculesen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1995-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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