A 2-D framework built from the tetranuclear Ag-4(2.2-dimethylglutarate)(2) oligomeric unit
| dc.contributor.author | Tsaousis, D. | en |
| dc.contributor.author | Michaelides, A. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.contributor.author | Raptopoulou, C. | en |
| dc.contributor.author | Terzis, A. | en |
| dc.date.accessioned | 2015-11-24T16:51:35Z | |
| dc.date.available | 2015-11-24T16:51:35Z | |
| dc.identifier.issn | 0022-4596 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9754 | |
| dc.rights | Default Licence | - |
| dc.subject | crystal-structure | en |
| dc.subject | silver(i) | en |
| dc.subject | coordination | en |
| dc.subject | complexes | en |
| dc.subject | network | en |
| dc.subject | polymer | en |
| dc.title | A 2-D framework built from the tetranuclear Ag-4(2.2-dimethylglutarate)(2) oligomeric unit | en |
| heal.abstract | The structure of the gel-grown coordination polymer Ag-4 (2,2-dimethylglutarate)(2) was determined by X-ray crystallography. It crystallizes in the monoclinic space group P2(1)/a, with a = 10.67(1) Angstrom, b = 6.334(6) Angstrom, c = 13.32(1) Angstrom, beta = 96.34(4)degrees, V = 895(2) Angstrom(3) and Z = 4. The structure is based on an unusual oligomeric unit, which was first found in silver(I) glutarate, and consists of a planar, centrosymmetric, tetranuclear silver cluster coordinated by two bridging ligands disposed at both sides of the metal plane. Additional Ag-O coordination bonds link the units together in a 2-D framework. Short metal-metal contacts in the range 2.81-3.40 Angstrom, are observed within the layers, suggesting that d(10)-d(10) interactions contribute to the stabilization of the structure. (C) 1997 Academic Press. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000072115400016 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S002245969797568X/1-s2.0-S002245969797568X-main.pdf?_tid=38da600f5281b6b1401b90eba4ec03cc&acdnat=1333040617_f13627994811a63bce5d59b320fc1950 | - |
| heal.journalName | Journal of Solid State Chemistry | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1997 | - |
| heal.publisher | Academic Press | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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