Synthesis, experimental and theoretical investigation of a new type nickel dithiolene complex
| dc.contributor.author | Soras, G. | en |
| dc.contributor.author | Psaroudakis, N. | en |
| dc.contributor.author | Manos, M. J. | en |
| dc.contributor.author | Tasiopoulos, A. J. | en |
| dc.contributor.author | Liakos, D. G. | en |
| dc.contributor.author | Mousdis, G. A. | en |
| dc.date.accessioned | 2015-11-24T16:49:34Z | |
| dc.date.available | 2015-11-24T16:49:34Z | |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9504 | |
| dc.rights | Default Licence | - |
| dc.subject | dithiolene complexes | en |
| dc.subject | uv-vis-nir spectra | en |
| dc.subject | ir and raman spectra | en |
| dc.subject | dft calculations | en |
| dc.subject | crystal structure | en |
| dc.subject | cyclic voltammetry | en |
| dc.subject | transition-metal dimers | en |
| dc.subject | gaussian-basis sets | en |
| dc.subject | electronic-properties | en |
| dc.subject | valence | en |
| dc.subject | energy | en |
| dc.subject | atoms | en |
| dc.subject | approximation | en |
| dc.subject | polarization | en |
| dc.subject | absorption | en |
| dc.subject | solvents | en |
| dc.title | Synthesis, experimental and theoretical investigation of a new type nickel dithiolene complex | en |
| heal.abstract | A new nickel complex with an extended multisulfur dithiolene ligand, [Ni(dmeodddt)(2)] (dmeodddt = 5,6-dimethoxy-5,6-dihydro-1,4-dithiine-2,3-dithiolate), has been synthesized and characterized by IR, Raman, UV-Vis and NMR spectroscopy. Its crystal structure has been determined by X-ray crystallography, showing that the Ni atom is tetra-coordinated and has a square planar geometry with the methoxy groups placed above and below the metal dithiolene core, due to stereochemical hindrance. Electrochemical measurements showed that the complex exhibits four 1e(-) reversible redox waves. The results of theoretical calculations showed a good agreement with the experimental findings and gave answers about its electronic structure. (c) 2013 Elsevier Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.poly.2013.06.033 | - |
| heal.identifier.secondary | <Go to ISI>://000324226200025 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538713004920/1-s2.0-S0277538713004920-main.pdf?_tid=73947aa4-3636-11e3-91f8-00000aab0f01&acdnat=1381909504_07c84a4e61dea4091bea2eb24768de14 | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2013 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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