Mercury(II)-carbon bond cleavage due to the coordination of the metal by 2-(2'-pyridyl)quinoxaline (L): Preparation and characterization of [Hg(2)I(4)L(2)] derived from the reaction of CH3HgI and L
| dc.contributor.author | Garoufis, A. | en |
| dc.contributor.author | Perlepes, S. P. | en |
| dc.contributor.author | Schreiber, A. | en |
| dc.contributor.author | Bau, R. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.date.accessioned | 2015-11-24T16:41:29Z | |
| dc.date.available | 2015-11-24T16:41:29Z | |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8427 | |
| dc.rights | Default Licence | - |
| dc.subject | crystal-structures | en |
| dc.subject | complexes | en |
| dc.subject | ligands | en |
| dc.title | Mercury(II)-carbon bond cleavage due to the coordination of the metal by 2-(2'-pyridyl)quinoxaline (L): Preparation and characterization of [Hg(2)I(4)L(2)] derived from the reaction of CH3HgI and L | en |
| heal.abstract | The 2:1 and 1:1 reactions of MeHgI with 2-(2'-pyridyl)quinoxaline (L) in methanol led to Hg-C bond cleavage and yielded the dinuclear complex [Hg(2)I(4)L(2)] as one of the products. The crystal structure of this compound shows a chelating behaviour of L and different (terminal, asymmetric bridging) iodide coordination modes. Some spectroscopic characteristics of the dimer and the biological relevance of this reaction are also reported. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1996TF22400001 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/027753879500259U/1-s2.0-027753879500259U-main.pdf?_tid=3fc96c1f2cfdb227dc184c705ab6ad6c&acdnat=1333029246_a6fb695df1bc7b5fa2dc4e383e182863 | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1996 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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