Comparative study of multielectron ionization of alkyl halides induced by picosecond laser irradiation

dc.contributor.authorKaziannis, S.en
dc.contributor.authorKosmidis, C.en
dc.date.accessioned2015-11-24T18:31:33Z
dc.date.available2015-11-24T18:31:33Z
dc.identifier.issn1089-5639-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16488
dc.rightsDefault Licence-
dc.subjectethyl-bromideen
dc.subjectdissociative ionizationen
dc.subjectpolyatomic-moleculesen
dc.subjectcoulomb explosionen
dc.subjectangular-distributionsen
dc.subjectphotodissociationen
dc.subjectionsen
dc.subjectfieldsen
dc.subjectdynamicsen
dc.subjectenergyen
dc.titleComparative study of multielectron ionization of alkyl halides induced by picosecond laser irradiationen
heal.abstractThe interaction of C2H5X, 1-C3H7X, 1-C4H9X, where X = I, Br, Cl, with strong (1 x 10(13)-1.2 x 10(14) W/cm(2)) 35 ps laser pulses at 1064 nm is studied by means of time-of-flight mass spectrometry. The multielectron ionization following the C-X bond elongation has been verified for the studied molecules. By combination of the intensity dependence of the ion yields, the estimated kinetic energies of the released fragment ions, and their angular distributions, we have identified the different dissociation channels of the transient multiply charged parent ions. From the dependence on the laser intensity of the ratio of the doubly charged halogen ions to the singly charged ones, it is concluded that the molecular coupling with the laser field increases with the molecular size.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Jp068300b-
heal.identifier.secondary<Go to ISI>://000245634700005-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/jp068300b-
heal.journalNameJournal of Physical Chemistry Aen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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