Clay-fulleropyrrolidine nanocomposites

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dc.contributor.authorGournis, D.en
dc.contributor.authorJankovic, L.en
dc.contributor.authorMaccallini, E.en
dc.contributor.authorBenne, D.en
dc.contributor.authorRudolf, P.en
dc.contributor.authorColomer, J. F.en
dc.contributor.authorSooambar, C.en
dc.contributor.authorGeorgakilas, V.en
dc.contributor.authorPrato, M.en
dc.contributor.authorFanti, M.en
dc.contributor.authorZerbetto, F.en
dc.contributor.authorSarova, G. H.en
dc.contributor.authorGuldi, D. M.en
dc.date.accessioned2015-11-24T17:32:34Z
dc.date.available2015-11-24T17:32:34Z
dc.identifier.issn0002-7863-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13748
dc.rightsDefault Licence-
dc.subjectself-assembled monolayersen
dc.subjectfullerene derivativesen
dc.subjectenergy minimizationen
dc.subjectazomethine ylidesen
dc.subjectmcm-41 materialsen
dc.subjectsmectite claysen
dc.subjectexcited-stateen
dc.subjectpillared clayen
dc.subjectc-60en
dc.subjectsurfaceen
dc.titleClay-fulleropyrrolidine nanocompositesen
heal.abstractIn this work, we describe the insertion of a water-soluble bisadduct fulleropyrrolidine derivative into the interlayer space of three layered smectite clays. The composites were characterized by a combination of powder X-ray diffraction, transmission electron microscopy, X-ray photoemission and FTIR spectroscopies, and laser flash photolysis measurements. The experiments, complemented by computer simulations, give insight into the formation process, structural details, and properties of the fullerene/clay nanocomposites. The reported composite materials constitute a new hybrid system, where C-60 differs from its crystals or its solutions, and open new perspectives for the design and construction of novel C-60-based organic/clay hybrid materials.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ja0579661-
heal.identifier.secondary<Go to ISI>://000237468900049-
heal.journalNameJ Am Chem Socen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2006-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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