Influence of Anion Exchange in Self-Assembling of Polymeric Ionic Liquid Block Copolymers

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dc.contributor.authorCarrasco, P. M.en
dc.contributor.authorde Luzuriaga, A. R.en
dc.contributor.authorConstantinou, M.en
dc.contributor.authorGeorgopanos, P.en
dc.contributor.authorRangou, S.en
dc.contributor.authorAvgeropoulos, A.en
dc.contributor.authorZafeiropoulos, N. E.en
dc.contributor.authorGrande, H. J.en
dc.contributor.authorCabanero, G.en
dc.contributor.authorMecerreyes, D.en
dc.contributor.authorGarcia, I.en
dc.date.accessioned2015-11-24T17:34:56Z
dc.date.available2015-11-24T17:34:56Z
dc.identifier.issn0024-9297-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14056
dc.rightsDefault Licence-
dc.subjectelectric-fieldsen
dc.subjectthin-filmsen
dc.subjectdendritic homopolymersen
dc.subjectpoly(ionic liquid)sen
dc.subjectgraft copolymeren
dc.subjecttemperatureen
dc.subjectmicrostructuresen
dc.subjectcatalysisen
dc.subjectwateren
dc.subjectnanocompositesen
dc.titleInfluence of Anion Exchange in Self-Assembling of Polymeric Ionic Liquid Block Copolymersen
heal.abstractA new technique for the modification of lamellar domain sizes in polymeric ionic liquid block copolymers has been proposed. Anion exchange in polymeric ionic liquids opens new ways to modify the sizes of lamella domains without modifying the ratio between the two different blocks of the neat copolymer. This study focuses on the influence of quaternization of poly(2-vinylpyridine) in poly(styrene-b-2-vinylpyridine) (PS-b-P2VP) and the effect of anion exchange in the nanostructured phases for thin films. The resulting materials obtained from the quaternization modification technique of the block copolymers and the anion exchange of the polymeric ionic liquid were characterized with Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and nuclear magnetic resonance (NMR). Furthermore, morphological characterization of the initial block polymer and several polymeric ionic liquid block copolymers has been carried out by atomic force microscopy (AFM) in order to analyze the influence of the anion in the nanostructures of these block copolymers.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ma200213s-
heal.identifier.secondary<Go to ISI>://000291895700049-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ma200213s-
heal.journalNameMacromoleculesen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2011-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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