Interaction of thioamides, selenoamides, and Amides with diiodine
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.date.accessioned | 2015-11-24T16:40:16Z | |
| dc.date.available | 2015-11-24T16:40:16Z | |
| dc.identifier.issn | 1565-3633 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8254 | |
| dc.rights | Default Licence | - |
| dc.subject | charge-transfer adducts | en |
| dc.subject | x-ray characterization | en |
| dc.subject | crystal-structure | en |
| dc.subject | antithyroid drugs | en |
| dc.subject | polyiodide salts | en |
| dc.subject | mechanism | en |
| dc.subject | iodine | en |
| dc.subject | i-2 | en |
| dc.subject | oxidation | en |
| dc.subject | complexes | en |
| dc.title | Interaction of thioamides, selenoamides, and Amides with diiodine | en |
| heal.abstract | We review the results of our work on the iodine interaction with thioamides, selenoamides, and amides. Complexes with (i) "spoke" or "extended spoke" structures, D . I(2) and D . I(2) . I(2), respectively, (D is the ligand donor) (ii) iodonium salts of {[D(2) - I](+)[I(n)](-)} (n = 3, 7) and {[D(2) - I](+)[ FeCl(4)](-)} formulae and (iii) disulfides of the categories (a) [D - D], (b) {[D - DH](+)[I(3)](-)} have been isolated and characterized. A compound of formula {[D(2) - I](+)[I(3)](-)[D.I(2)]} containing both types of complexes (i) and ( ii) was also isolated. The interaction of diiodine with selenium analogs of the antithyroid drug 6-n-propyl-2-thiouracil (PTU), of formulae RSeU (6-alkyl-2-Selenouracil) results in the formation of complexes with formulae [(RSeU) I2]. All these results are correlated with the mechanism of action of antithyroid drugs. Finally, we review here our work on the diiodine interaction with the amides (LO). | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1155/Bca/2006/60291 | - |
| heal.identifier.secondary | <Go to ISI>://000252007100001 | - |
| heal.identifier.secondary | http://downloads.hindawi.com/journals/bca/2006/060291.pdf | - |
| heal.journalName | Bioinorg Chem Appl | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2006 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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