Two-photon spectroscopy of styrene: detection of the 3p Rydberg states

dc.contributor.authorPaleologos, A.en
dc.contributor.authorPhilis, J. G.en
dc.date.accessioned2015-11-24T18:39:39Z
dc.date.available2015-11-24T18:39:39Z
dc.identifier.issn0022-2860-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17476
dc.rightsDefault Licence-
dc.subjectstyreneen
dc.subjectvuv spectrumen
dc.subjectrempien
dc.subjectrydberg statesen
dc.subjectexcited singlet-statesen
dc.subjectmulti-photon ionizationen
dc.subjectphotoelectron-spectroscopyen
dc.subjectabsorption-spectroscopyen
dc.subjectmultiphoton ionizationen
dc.subjectab-initioen
dc.subjectspectraen
dc.subjectbenzeneen
dc.subjectphenylacetyleneen
dc.subjectfluorescenceen
dc.titleTwo-photon spectroscopy of styrene: detection of the 3p Rydberg statesen
heal.abstractResonance enhanced multiphoton ionization spectroscopy, (2 + 1) REMPI, has been employed in jet cooled styrene vapors for the detection of Rydberg states. A resonance appears at 50,484 cm(-1) and is interpreted as a 3p <- HOMO Rydberg transition (delta = 0.52). The 3s state was not detected in the REMPI experiments. The comparison of the experimental spectrum of styrene, in the energy region 5.3-6.6 eV, with two theoretical works from the literature (CASPT2 and SAC-Cl) shows that the CASPT2 results are very close to the experiment and more reliable than the SAC-Sl. (c) 2004 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.molstruc.2004.10.106-
heal.identifier.secondary<Go to ISI>://000229657700013-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0022286004008361/1-s2.0-S0022286004008361-main.pdf?_tid=c50620c542f74250e20f0083f53486ac&acdnat=1334231774_86d4ff5b55fa4ca38223cdd0cad181d8-
heal.journalNameJournal of Molecular Structureen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2005-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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