Interactions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base: New Lanthanide(III) Complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)

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dc.contributor.authorTsiouri, M.en
dc.contributor.authorSkorda, K.en
dc.contributor.authorPapadimitriou, C.en
dc.contributor.authorLi, Y.en
dc.contributor.authorWoollins, J. D.en
dc.contributor.authorPlakatouras, J. C.en
dc.date.accessioned2015-11-24T16:40:21Z
dc.date.available2015-11-24T16:40:21Z
dc.identifier.issn1565-3633-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8264
dc.rightsDefault Licence-
dc.subjectcrystal-structureen
dc.subjectmacrocyclic complexen
dc.subjectmetal-complexesen
dc.subjectligandsen
dc.subjecteuropium(iii)en
dc.subjectneodymium(iii)en
dc.subjectyttrium(iii)en
dc.subjectluminescenceen
dc.subjectcopper(ii)en
dc.subjectnickel(ii)en
dc.titleInteractions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base: New Lanthanide(III) Complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)en
heal.abstractThe novel lanthanide(III) complexes [Ln(NO(3))(2)L](NO(3))center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO(3))(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 4 was also characterized with crystallographic studies: orthorhombic P2(1)2(1)2(1), a = 10.6683(14), b = 13.4752(15), c = 19.3320(26) angstrom. In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1155/2010/613140-
heal.identifier.secondary<Go to ISI>://000280796900001-
heal.identifier.secondaryhttp://downloads.hindawi.com/journals/bca/2010/613140.pdf-
heal.journalNameBioinorg Chem Applen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2010-
heal.publisherHindawi Publishing Corporationen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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