Hydrocarbon oxidation by homogeneous and heterogeneous non-heme iron (III) catalysts with H2O2
| dc.contributor.author | Bilis, G. | en |
| dc.contributor.author | Christoforidis, K. C. | en |
| dc.contributor.author | Deligiannakis, Y. | en |
| dc.contributor.author | Louloudi, M. | en |
| dc.date.accessioned | 2015-11-24T16:39:12Z | |
| dc.date.available | 2015-11-24T16:39:12Z | |
| dc.identifier.issn | 0920-5861 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8130 | |
| dc.rights | Default Licence | - |
| dc.subject | non-heme iron | en |
| dc.subject | biomimetic catalysis | en |
| dc.subject | hydrocarbon oxidation | en |
| dc.subject | h2o2 | en |
| dc.subject | fe-ooh | en |
| dc.subject | low spin fe | en |
| dc.subject | electron-paramagnetic-resonance | en |
| dc.subject | olefin cis-dihydroxylation | en |
| dc.subject | spin iron(iii) complexes | en |
| dc.subject | dioxygen activation | en |
| dc.subject | methane monooxygenase | en |
| dc.subject | alkane hydroxylation | en |
| dc.subject | hydrogen-peroxide | en |
| dc.subject | chemistry | en |
| dc.subject | enzymes | en |
| dc.subject | epoxidation | en |
| dc.title | Hydrocarbon oxidation by homogeneous and heterogeneous non-heme iron (III) catalysts with H2O2 | en |
| heal.abstract | Homogeneous (LFeIII) and heterogeneous (LFeIII SiO2) [L = 3-{2-[2-(3-hydroxy-1 3-diphenyl-allylideneamino)-ethylamino]-ethylimino}-1 3-diphenyl propen-1-ol] catalysts have been synthesized and evaluated catalytically In CH3CN both the homogeneous and heterogeneous catalysts were efficient in alkene oxidations Cyclohexane oxidation provides total yield of 12 1% and 73% with an alcohol/ketone (A/K) ratio of 1 75 and 1 60 by the LFeIII and the LFeIII SiO2 catalysts respectively UV-vis kinetic data suggest formation of LFeIII-OOH species EPR data show that in the presence of CH3CN low-spin Fe-III (S = 1/2) centers are formed which are responsible for the catalytic activity The heterogeneous LFe SiO2 catalyst tested up to 5 re-uses shows a total yield loss similar to 4% per use providing the same distribution of oxidation products (C) 2010 Elsevier B V All rights reserved | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.cattod.2010.03.063 | - |
| heal.identifier.secondary | <Go to ISI>://000284502000018 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0920586110002439/1-s2.0-S0920586110002439-main.pdf?_tid=1a4e9b34-362f-11e3-9381-00000aacb35d&acdnat=1381906348_6c669982aecab1c9824e411550e9514c | - |
| heal.journalName | Catalysis Today | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2010 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: