Palladium(II) and platinum(II) complexes of 2-hydroxy acetophenone N(4)-ethylthiosemicarbazone - crystal structure and description of bonding properties
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Papathanasis, L.
Demertzis, M. A.
Yadav, P. N.
Kovala-Demertzi, D.
Prentjas, C.
Castineiras, A.
Skoulika, S.
West, D. X.
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peer reviewed
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Inorganica Chimica Acta
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Description
Reaction of H2PtCl4 and K2PdCl4 with 2-hydroxyacetophenone N(4)-ethylthiosenticarbazone, H(2)Ap4Et, afforded [Pt(Ap4Et)(H(2)Ap4Et)] and [Pd(Ap4Et)(H(2)Ap4Et)]. Their crystal and molecular structures are reported and represent the first 1:2 thiosemicarbazone complexes with ligands having both different formal charge and denticity. The dianion, Ap4Et(2-), coordinates in a planar conformation to palladium(II) or platinum(II) via the phenolato 0, imine N and thiolato S atoms, while the neutral molecule exhibits monodentate coordination by the thione S atom. Intra-, intermolecular hydrogen bonds and C-H... pi contacts lead to aggregation and a supramolecular assembly. Electronic, IR, and NMR spectral data, as well as electrochemical measurements, are included. The pK(a) values of the poorly water soluble H2Ap4Et were obtained spectrophotometrically in aqueous solutions of constant ionic strength. (C) 2004 Elsevier B.V. All rights reserved.
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palladium(ii), platinum(ii), thiosemicarbazone, crystal structures, spectroscopy, protonation constants, 2-hydroxyacetophenone n-4-substituted thiosemicarbazones, copper(ii) complexes, tripalladium complex, ligands, adducts
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<Go to ISI>://000225452100008
http://ac.els-cdn.com/S0020169304003202/1-s2.0-S0020169304003202-main.pdf?_tid=4f96ef7702e2033eb93afc8c8d474399&acdnat=1333028884_a18eacc865e13209876a7e31c5952020
http://ac.els-cdn.com/S0020169304003202/1-s2.0-S0020169304003202-main.pdf?_tid=4f96ef7702e2033eb93afc8c8d474399&acdnat=1333028884_a18eacc865e13209876a7e31c5952020
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en
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Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας