Heterogeneous clay-manganese(II) oxidation catalyst

dc.contributor.authorGournis, D.en
dc.contributor.authorLouloudi, M.en
dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorKolokytha, C.en
dc.contributor.authorMitopoulou, K.en
dc.contributor.authorHadjiliadis, N.en
dc.date.accessioned2015-11-24T16:38:46Z
dc.date.available2015-11-24T16:38:46Z
dc.identifier.issn0928-4931-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8082
dc.rightsDefault Licence-
dc.subjectbiomimetic oxidation catalystsen
dc.subjectclay compositesen
dc.subjectschiff base complexesen
dc.subjectmontmorilloniteen
dc.subjectenantioselective epoxidation catalystsen
dc.subjecthydrogen-peroxideen
dc.subjectmanganese porphyrinsen
dc.subjectcomplexesen
dc.subjectclayen
dc.subjecthydrocarbonsen
dc.subjectalkeneen
dc.subjectsitesen
dc.subjecth2o2en
dc.titleHeterogeneous clay-manganese(II) oxidation catalysten
heal.abstractA manganese(II)-Schiff base complex has been heterogenized by its intercalation into clay minerals. The incorporation of the homogeneous manganese(II) complexes in the interlayer space of aluminosilicate mineral is accomplished by a cation exchange process. The obtained clay-manganese(II) composite has been studied by chemical analysis, X-ray diffraction and FT-IR spectroscopy. The new catalytic material has been evaluated as oxidation catalyst. Our results showed that this composite exhibits significant catalytic activities for alkene epoxidation using hydrogen peroxide as oxidant. (C) 2002 Elsevier Science B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1016/S0928-4931(02)00104-2-
heal.identifier.secondary<Go to ISI>://000178156300019-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0928493102001042/1-s2.0-S0928493102001042-main.pdf?_tid=b63bd15c-362e-11e3-83a5-00000aab0f27&acdnat=1381906180_8bb6311d0534d8b9fa137c6d7beaa6e3-
heal.journalNameMaterials Science & Engineering C-Biomimetic and Supramolecular Systemsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2002-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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