Displacement of triphenylphosphine from Cu(PPh3)(2)NO3 and Co(PPh3)(2)Cl-2 by a diselenoimidodiphosphinato ligand. X-ray crystal structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph-2] and Co[Ph2P(Se)NP(Se)Ph-2](2) containing the novel CuSe2P2N and CoSe2P2N inorganic metallocycles

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dc.contributor.authorNovosad, J.en
dc.contributor.authorNecas, M.en
dc.contributor.authorMarek, J.en
dc.contributor.authorVeltsistas, P.en
dc.contributor.authorPapadimitriou, C.en
dc.contributor.authorHaiduc, I.en
dc.contributor.authorWatanabe, M.en
dc.contributor.authorWoollins, J. D.en
dc.date.accessioned2015-11-24T16:56:25Z
dc.date.available2015-11-24T16:56:25Z
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10437
dc.rightsDefault Licence-
dc.subjectcrystal structuresen
dc.subjectcopper complexesen
dc.subjectdiselenoimidodiphosphinato complexesen
dc.subjectfree chelate ringsen
dc.subjectmolecular-structureen
dc.subjectpolyfunctional moleculesen
dc.subjectmetal-complexesen
dc.subjectderivativesen
dc.subjectcompounden
dc.subjectcoreen
dc.subjectreactivityen
dc.subjectchemistryen
dc.subjectsulfuren
dc.titleDisplacement of triphenylphosphine from Cu(PPh3)(2)NO3 and Co(PPh3)(2)Cl-2 by a diselenoimidodiphosphinato ligand. X-ray crystal structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph-2] and Co[Ph2P(Se)NP(Se)Ph-2](2) containing the novel CuSe2P2N and CoSe2P2N inorganic metallocyclesen
heal.abstractThe reaction of Cu(PPh3)(2)NO3 with K[Ph2P(Se)-N-P(Se)Ph-2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph-2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent: gave with Co(PPh3)(2)Cl-2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph-2](2), containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations. (C) 1999 Elsevier Science S.A. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://000081407600018-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169399001541/1-s2.0-S0020169399001541-main.pdf?_tid=bf0bfad6ffd5ca7fd23e5c106d51a24d&acdnat=1335451792_9ad823b5b1574ed93a3666bd8578d758-
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1999-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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