Investigation of the electronic vibrational structure of furan by REMPI

dc.contributor.authorPhilis, J. G.en
dc.date.accessioned2015-11-24T18:26:43Z
dc.date.available2015-11-24T18:26:43Z
dc.identifier.issn1386-1425-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/15937
dc.rightsDefault Licence-
dc.subjectfuranen
dc.subjectrydberg statesen
dc.subjectvibrational structureen
dc.subjectrempien
dc.subjectphotodissociationen
dc.subjectchen
dc.subjectenergy-loss spectroscopyen
dc.subjectenhanced multiphoton ionizationen
dc.subjectpyrroleen
dc.subjectabsorptionen
dc.subjectspectrumen
dc.subjectstatesen
dc.subjectc4h4oen
dc.subjectderivativesen
dc.titleInvestigation of the electronic vibrational structure of furan by REMPIen
heal.abstractResonance-enhanced multiphoton ionization (REMPI) has been applied to detect the hot bands as well as the cold bands of the 1a(2) ->-> 3d(xy)((1)A(1)) Rydberg transition of furan (jet-cooled, mass-analyzed). Based on the unambiguous assignment of the hot bands, a complete vibronic analysis is given for the cold bands of this transition (up to 4600 cm(-1) above the origin). This analysis can be used for the interpretation of the vibrational structure in the X 2A(2) photoelectron band. The energy ordering of the five 3d Rydberg states is 1A(2) approximate to 2A(2) < A1 < B-1 < B-2. It is also shown that neutral CH is produced in the UV laser multiphoton photodecomposition of furan. (C) 2006 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.saa.2006.10.024-
heal.identifier.secondary<Go to ISI>://000248625200031-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1386142506006020/1-s2.0-S1386142506006020-main.pdf?_tid=43850cffce716b5c16c408fb338171b6&acdnat=1334231835_0daf36b48e44b42be613c77ec53958f3-
heal.journalNameSpectrochimica Acta Part a-Molecular and Biomolecular Spectroscopyen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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