Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H(2)O)]center dot 3(H(2)O)}2 (H(3)L = trans-aconitic acid)

dc.contributor.authorKostakis, G. E.en
dc.contributor.authorNordlander, E.en
dc.contributor.authorTsipis, A. C.en
dc.contributor.authorHaukka, M.en
dc.contributor.authorPlakatouras, J. C.en
dc.date.accessioned2015-11-24T16:49:39Z
dc.date.available2015-11-24T16:49:39Z
dc.identifier.issn1387-7003-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9515
dc.rightsDefault Licence-
dc.subjecthexameric water clusteren
dc.subjectzinc(ii)en
dc.subject3d metal-supramolecular architectureen
dc.subjecth-bonden
dc.subjectcrystal structureen
dc.subjecticeen
dc.subjectcomplexesen
dc.subjectnetworksen
dc.subjectpolymersen
dc.subjectliganden
dc.subjecthosten
dc.subjectbulken
dc.subjectionsen
dc.subjecttapeen
dc.titleSynthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H(2)O)]center dot 3(H(2)O)}2 (H(3)L = trans-aconitic acid)en
heal.abstractThe reaction of Zn(NO(3))(2)center dot 3(H(2)O) with trans-aconitic acid (H(3)L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H(2)O)]center dot 3(H(2)O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.inoche.2010.09.038-
heal.identifier.secondary<Go to ISI>://000287269000022-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1387700310004429/1-s2.0-S1387700310004429-main.pdf?_tid=338c48c6e25e6ef916481b2b630de087&acdnat=1333035892_386691e100c298496a931d0958dcac60-
heal.journalNameInorganic Chemistry Communicationsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2011-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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