p-hydroquinone-metal compounds: synthesis and crystal structure of two novel V-V-p-hydroquinonate and V-IV-p-semiquinonate species

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dc.contributor.authorDrouza, C.en
dc.contributor.authorTolis, V.en
dc.contributor.authorGramlich, V.en
dc.contributor.authorRaptopoulou, C.en
dc.contributor.authorTerzis, A.en
dc.contributor.authorSigalas, M. P.en
dc.contributor.authorKabanos, T. A.en
dc.contributor.authorKeramidas, A. D.en
dc.date.accessioned2015-11-24T16:44:52Z
dc.date.available2015-11-24T16:44:52Z
dc.identifier.issn1359-7345-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8842
dc.rightsDefault Licence-
dc.subjectray-absorption spectroscopyen
dc.subjectamine oxidasesen
dc.subjectelectronic-structureen
dc.subjectcomplexesen
dc.subjectcatecholen
dc.subjecttitaniumen
dc.subjectcentersen
dc.subjectcobalten
dc.titlep-hydroquinone-metal compounds: synthesis and crystal structure of two novel V-V-p-hydroquinonate and V-IV-p-semiquinonate speciesen
heal.abstractReaction of the p-hydroquinone derivative H(2)Na(4)bi-cah. 4H(2)O with either (VOSO4)-O-IV.3H(2)O and (NaVO3)-O-V in equivalent quantities or with (NaVO3)-O-V yields the tetranuclear (VO2+)-O-IV macrocycle-semiquinonate compound Na-6{((VO)-O-IV)4-( mu(2)-O)(2)[mu(2)-bicas.(-5)-N,O,O,O](2)}.Na2SO4.20H(2)O (1.Na2SO4. 20H(2)O) and the dinuclear cis-(VO2+)-O-V-hydroquinone species Na4{((VO2)-O-V)(2)[mu(2)-bicah(-6)-N,O,O,O]}.11H(2)O (2.11H(2)O) respectively. Compounds 1.Na2SO4.20H(2)O and 2.11H(2)O were characterized by X-ray structure analysis and ab initio calculations.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1039/B207330g-
heal.identifier.secondary<Go to ISI>://000179321600016-
heal.identifier.secondaryhttp://pubs.rsc.org/en/content/articlepdf/2002/cc/b207330g-
heal.journalNameChemical Communicationsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2002-
heal.publisherRoyal Society of Chemistryen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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