Infrared reflectance study of thermally treated Li- and Cs-montmorillonites

dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorPetridis, D.en
dc.contributor.authorGournis, D.en
dc.date.accessioned2015-11-24T17:35:06Z
dc.date.available2015-11-24T17:35:06Z
dc.identifier.issn0009-8604-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14075
dc.rightsDefault Licence-
dc.subjectcs-montmorilloniteen
dc.subjectli-montmorilloniteen
dc.subjectlongitudinal-optic (lo) modeen
dc.subjectmigrationen
dc.subjectreflectivityen
dc.subjecttransverse-optic (to) modeen
dc.subjectsynthetic fluorine micasen
dc.subjectir-spectraen
dc.subjectglassesen
dc.subjectsilicaen
dc.subjectchargeen
dc.subjectspectroscopyen
dc.subjectmigrationen
dc.subjectlithiumen
dc.subjectwateren
dc.subjectsitesen
dc.titleInfrared reflectance study of thermally treated Li- and Cs-montmorillonitesen
heal.abstractThe structure of Li-and Cs-montmorillonites was studied using infrared (IR) reflectance spectroscopy. The spectra of heat-treated clays between 80 and 220 degrees C were analyzed by Kramers-Kronig inversion in order to obtain the optical and dielectric properties of the clays. The analysis revealed the transverse-optic (TO) and longitudinal-optic (LO) components of the asymmetric stretching vibration of Si-O-Si bridges. Major differences, in particular the systematic development of new bands, were found in the Li-montmorillonite LO and TO spectra with increasing temperature. These changes were attributed to the migration of the Li-cations into the layer structure.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://A1997YJ80800004-
heal.journalNameClays and Clay Mineralsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1997-
heal.publisherClay Minerals Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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