Metalloporphyrinosilicas: A new class of hybrid organic-inorganic materials acting as selective biomimetic oxidation catalysts
| dc.contributor.author | Battioni, P. | en |
| dc.contributor.author | Cardin, E. | en |
| dc.contributor.author | Louloudi, M. | en |
| dc.contributor.author | Schollhorn, B. | en |
| dc.contributor.author | Spyroulias, G. A. | en |
| dc.contributor.author | Mansuy, D. | en |
| dc.contributor.author | Traylor, T. G. | en |
| dc.date.accessioned | 2015-11-24T16:41:34Z | |
| dc.date.available | 2015-11-24T16:41:34Z | |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8441 | |
| dc.rights | Default Licence | - |
| dc.subject | complexes | en |
| dc.title | Metalloporphyrinosilicas: A new class of hybrid organic-inorganic materials acting as selective biomimetic oxidation catalysts | en |
| heal.abstract | New hybrid organic-inorganic materials are prepared by hydrolysis and polycondensation, or cocondensation with tetraethoxysilane, of iron porphyrins bearing a trifluorosilyl function; despite their insolubility, these 'metalloporphyrinosilicas' are efficient catalysts for alkene epoxidation by PhIO or Bu(t)OOH and alkane hydroxylation by PhIO, the iron porphyrinosilicas with low specific surface areas (approximate to 60 m(2) g(-1)) catalysing a shape-selective hydroxylation of alkane mixtures. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1039/Cc9960002037 | - |
| heal.identifier.secondary | <Go to ISI>://A1996VG30300020 | - |
| heal.identifier.secondary | http://pubs.rsc.org/en/Content/ArticleLanding/1996/CC/cc9960002037 | - |
| heal.journalName | Chemical Communications | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1996 | - |
| heal.publisher | Royal Society of Chemistry | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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