Di(2-ethylhexyl) adipate migration from PVC-cling film into packaged sea bream (Sparus aurata) and rainbow trout (Oncorhynchus mykiss) fillets: kinetic study and control of compliance with EU specifications
Φόρτωση...
Ημερομηνία
Συγγραφείς
Goulas, A. E.
Salpea, E.
Kontominas, M. G.
Τίτλος Εφημερίδας
Περιοδικό ISSN
Τίτλος τόμου
Εκδότης
Περίληψη
Τύπος
Είδος δημοσίευσης σε συνέδριο
Είδος περιοδικού
peer reviewed
Είδος εκπαιδευτικού υλικού
Όνομα συνεδρίου
Όνομα περιοδικού
European Food Research and Technology
Όνομα βιβλίου
Σειρά βιβλίου
Έκδοση βιβλίου
Συμπληρωματικός/δευτερεύων τίτλος
Περιγραφή
Polyvinyl chloride (PVC) film containing di(2-ethylhexyl) adipate (DEHA) plasticizer was used to wrap sea bream (Sparus aurata) and rainbow trout (Oncorhynchus mykiss) fillet samples with and without skin. After wrapping the samples were stored at 2 +/- 0.5 degrees C and analyzed for DEHA content at time intervals between 5 and 360 h of contact (kinetic study). Determination of DEHA was performed using a direct gas chromatography (GC) method. Statistically significant differences (p < 0.05) in migration of DEHA were observed between the two fish fillet samples: the mean equilibrium migration amount of DEHA in sea bream was 2.93 mg/dm(2) film (91.9 mg/kg fillet) corresponding to a loss of 19.0% (w/w) DEHA from PVC film; while the mean equilibrium amount of DEHA in rainbow trout was 3.74 mg/dm(2) (117.6 mg/kg) corresponding to a loss of 23.9% (w/w) DEHA. The above values for DEHA in sea bream are very close to the limit of 3 mg/dm(2) of film surface set by the EU for DEHA while the corresponding migration values for rainbow trout exceeded this limit. Diffusion coefficients for DEHA in the PVC film during contact with both fish fillets were calculated and found significantly different between two fish samples. Furthermore, the presence of skin on the fillet decreased migration of DEHA into the fish flesh by a factor of 2.4-2.8. Based on equilibrium migration values of DEHA it is concluded that for a 60-kg adult, a daily consumption of 150 g rainbow trout or 200 g sea bream fillet packaged in PVC film would result in a daily intake of DEHA close to the tolerable daily intake (TDI) of 0.3 mg/kg body weight set by the EU.
Περιγραφή
Λέξεις-κλειδιά
fish fillets, di(2-ethylhexyl) adipate, migration, diffusion coefficient, pvc film, polyvinyl-chloride film, food-grade pvc, acetyltributyl citrate plasticizers, gamma-radiation, sensory attributes, electron-beam, olive oil, rats, simulants, di-(2-ethylhexyl)adipate
Θεματική κατηγορία
Παραπομπή
Σύνδεσμος
<Go to ISI>://000252540000034
http://www.springerlink.com/content/h1v7u4k1t8381h40/fulltext.pdf
http://www.springerlink.com/content/h1v7u4k1t8381h40/fulltext.pdf
Γλώσσα
en
Εκδίδον τμήμα/τομέας
Όνομα επιβλέποντος
Εξεταστική επιτροπή
Γενική Περιγραφή / Σχόλια
Ίδρυμα και Σχολή/Τμήμα του υποβάλλοντος
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας