Model studies of the interaction of vanadium(III) and oxovanadium(IV/V) with the carbonyl amide oxygen
dc.contributor.author | Soulti, K. D. | en |
dc.contributor.author | Troganis, A. | en |
dc.contributor.author | Papaioannou, A. | en |
dc.contributor.author | Kabanos, T. A. | en |
dc.contributor.author | Keramidas, A. D. | en |
dc.contributor.author | Deligiannakis, Y. G. | en |
dc.contributor.author | Raptopoulou, C. P. | en |
dc.contributor.author | Terzis, A. | en |
dc.date.accessioned | 2015-11-24T16:41:58Z | |
dc.date.available | 2015-11-24T16:41:58Z | |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8496 | |
dc.rights | Default Licence | - |
dc.subject | protein interactions | en |
dc.subject | labile oxovanadates | en |
dc.subject | biological-systems | en |
dc.subject | crystal-structure | en |
dc.subject | binding-sites | en |
dc.subject | solid-state | en |
dc.subject | complexes | en |
dc.subject | vanadate | en |
dc.subject | peptides | en |
dc.subject | chemistry | en |
dc.title | Model studies of the interaction of vanadium(III) and oxovanadium(IV/V) with the carbonyl amide oxygen | en |
heal.abstract | A series of vanadium(III) and oxovanadium(IV/V) compounds with the ligands, N-(2-nitrophenyl)pyridine-2-carboxamide (Hpycan), N-(phenyl)pyridine-2-carboxamide (Hpheca), and N-(2-pyridyl)acetamide (Hpyra), containing the amide functionality, was prepared and characterized both in solution and in solid state. All vanadium compounds contain a vanadium-amide oxygen bond. Crystal data for [VOCl(2)(OC(2)H(5))(Hpheca)] (4) are monoclinic; P2(1)/a; a = 12.668(5) Angstrom, b = 8.084(3) Angstrom, c = 17.222(6) Angstrom, alpha = 108.148(12)degrees; Z = 4. In addition to the synthesis and crystallographic studies, the optical, infrared, and magnetic properties of these compounds are reported. Electron paramagnetic resonance [of oxovanadium(IV) species] and (1)H, (13)C{(1)H}, and (51)V nuclear magnetic resonance [of oxovanadium(V) compounds] properties are reported as well. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.secondary | <Go to ISI>://000077839100033 | - |
heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ic9714302 | - |
heal.journalName | Inorg Chem | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1998 | - |
heal.publisher | American Chemical Society | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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