alpha-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn-9(III) Complex

dc.contributor.authorKoumousi, E. S.en
dc.contributor.authorManos, M. J.en
dc.contributor.authorLampropoulos, C.en
dc.contributor.authorTasiopoulos, A. J.en
dc.contributor.authorWernsdorfer, W.en
dc.contributor.authorChristou, G.en
dc.contributor.authorStamatatos, T. C.en
dc.date.accessioned2015-11-24T16:45:40Z
dc.date.available2015-11-24T16:45:40Z
dc.identifier.issn0020-1669-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8965
dc.rightsDefault Licence-
dc.subjectsingle-molecule magnetsen
dc.subjecthigh-spin moleculesen
dc.subjectmanganese clustersen
dc.subjectcarboxylateen
dc.subjectligandsen
dc.titlealpha-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn-9(III) Complexen
heal.abstractThe initial employment of alpha-benzoin oxime (bzoxH(2)) in higher oxidation state 3d metal cluster chemistry has provided access to a new enneanuclear Mn-III complex with an unprecedented metal-core topology consisting of two triangular [Mn-3(mu(3)-O2-)(mu-ON)(3)](4+) fragments connected by a linear [Mn-3(mu-ON)(6)](3+) unit. The Mn-9(III) cluster is antiferromagnetically coupled and has an S=3 spin ground state.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ic100178y-
heal.identifier.secondary<Go to ISI>://000276073000003-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ic100178y-
heal.journalNameInorg Chemen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2010-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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