alpha-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn-9(III) Complex
dc.contributor.author | Koumousi, E. S. | en |
dc.contributor.author | Manos, M. J. | en |
dc.contributor.author | Lampropoulos, C. | en |
dc.contributor.author | Tasiopoulos, A. J. | en |
dc.contributor.author | Wernsdorfer, W. | en |
dc.contributor.author | Christou, G. | en |
dc.contributor.author | Stamatatos, T. C. | en |
dc.date.accessioned | 2015-11-24T16:45:40Z | |
dc.date.available | 2015-11-24T16:45:40Z | |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8965 | |
dc.rights | Default Licence | - |
dc.subject | single-molecule magnets | en |
dc.subject | high-spin molecules | en |
dc.subject | manganese clusters | en |
dc.subject | carboxylate | en |
dc.subject | ligands | en |
dc.title | alpha-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn-9(III) Complex | en |
heal.abstract | The initial employment of alpha-benzoin oxime (bzoxH(2)) in higher oxidation state 3d metal cluster chemistry has provided access to a new enneanuclear Mn-III complex with an unprecedented metal-core topology consisting of two triangular [Mn-3(mu(3)-O2-)(mu-ON)(3)](4+) fragments connected by a linear [Mn-3(mu-ON)(6)](3+) unit. The Mn-9(III) cluster is antiferromagnetically coupled and has an S=3 spin ground state. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.primary | Doi 10.1021/Ic100178y | - |
heal.identifier.secondary | <Go to ISI>://000276073000003 | - |
heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ic100178y | - |
heal.journalName | Inorg Chem | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 2010 | - |
heal.publisher | American Chemical Society | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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