Synthesis, spectroscopic and computational studies plus crystal structure of [(bis-benzo-1,3-thiazolidine-2-thione) (bis-triphenylphoshine)copper(I)] [chloro(benzothiazolidine-2-thione)(bis-triphenylphoshine)copper(I)]
| dc.contributor.author | Cox, P. J. | en |
| dc.contributor.author | Aslanidis, P. | en |
| dc.contributor.author | Karagiannidis, P. | en |
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.date.accessioned | 2015-11-24T16:49:36Z | |
| dc.date.available | 2015-11-24T16:49:36Z | |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9508 | |
| dc.rights | Default Licence | - |
| dc.subject | copper(i) complexes | en |
| dc.subject | benz-1,3-thiazolidine-2-thione | en |
| dc.subject | triphenylphoshine | en |
| dc.subject | crystal structure | en |
| dc.subject | heterocyclic thiones | en |
| dc.subject | coordination-compounds | en |
| dc.subject | copper(i) complexes | en |
| dc.subject | cu(i) complexes | en |
| dc.subject | metal-complexes | en |
| dc.subject | tolylphosphine | en |
| dc.subject | phosphines | en |
| dc.title | Synthesis, spectroscopic and computational studies plus crystal structure of [(bis-benzo-1,3-thiazolidine-2-thione) (bis-triphenylphoshine)copper(I)] [chloro(benzothiazolidine-2-thione)(bis-triphenylphoshine)copper(I)] | en |
| heal.abstract | Treatment of [Cu(PPh3)(3)Cl] (PPh3 = triphenylphosphine) in acetonitrile/methanol solvent with benz-1,3-thiazolidine-2-thione (bzthztH) yielded, depending on the reactions stoichiometry, two different products. The reaction in a 1:2 metal-thione ratio yielded a product of the formula {[Cu(PPh3)(2)(bztzdtH)Cl][Cu(PPh3)(2)(bztzdtH)(2)]}, while the reaction in a 1:3 metal-thione ratio resulted in the total elimination of the phosphine ligands to give the mononuclear complex [Cu(bztzdtH)(3)Cl]. The complexes were characterized by their IR, UV-Vis and H-1-NMR spectroscopic data. The crystal structure of {[Cu(PPh3)(2)(bztzdtH)(2)][Cu(PPh3)(2)(bztzdtH)Cl]} was determined by single crystal X-ray diffraction methods. The unit cell contains two different molecules [Cu(PPh3)(2)(bztzdtH)(2)] (hereafter molecule A) and [Cu(PPh3)(2)(bztzdtH)Cl] (hereafter molecule B). In both of the molecules, copper(I) atoms display a distorted tetrahedral environment. In the CuP2S2 core of molecule A, Cu-P bond lengths are 2.285(2) and 2.281(2) Angstrom, while Cu-S bond distances are 2.364(2) and 2.386(2) Angstrom. In molecule B, the tetrahedral arrangement around the copper(I) atom is formed by two P atoms from triphenyl-phosphine with Cu-P bond distances of 2.269(2) and 2.285(3) Angstrom, one Cl atom (Cu-Cl=2.40 Angstrom) and one S atom from the thione ligand and [Cu-S=2.36(4) Angstrom]. (C) 1999 Elsevier Science Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000080324800019 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538799000182/1-s2.0-S0277538799000182-main.pdf?_tid=eac914541cda752ef9dc9cf45a651424&acdnat=1333030109_eb2ccf31cab42fe32e1dbaf574a04605 | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1999 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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