Effects of pressure on systems with intrinsic orientational order
| dc.contributor.author | Floudas, G. | en |
| dc.date.accessioned | 2015-11-24T18:29:33Z | |
| dc.date.available | 2015-11-24T18:29:33Z | |
| dc.identifier.issn | 0079-6700 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/16270 | |
| dc.rights | Default Licence | - |
| dc.subject | shape-persistent macromolecules | en |
| dc.subject | liquid crystalline polymers | en |
| dc.subject | hairy-rod polymers | en |
| dc.subject | polypeptides | en |
| dc.subject | glass transition | en |
| dc.subject | phase state | en |
| dc.subject | liquid-crystalline polymers | en |
| dc.subject | nuclear-magnetic-resonance | en |
| dc.subject | electric dipole moment | en |
| dc.subject | mesogenic side groups | en |
| dc.subject | glass-transition | en |
| dc.subject | solid-state | en |
| dc.subject | dielectric-relaxation | en |
| dc.subject | molecular-dynamics | en |
| dc.subject | polypeptide solutions | en |
| dc.subject | neutron-scattering | en |
| dc.title | Effects of pressure on systems with intrinsic orientational order | en |
| heal.abstract | The dynamics of shape-persistent macromolecules have not been investigated to the same extent as of glass-forming liquids or amorphous polymers. Herein we investigate the dynamics of systems possessing intrinsic orientational order. Do such systems exhibit a glass transition and if yes, what is its origin? Do they show a dual relaxation scenario (alpha and beta-processes) as glass-forming liquids and polymers? If such processes exists what is their pressure dependence? Is the a-process controlled by temperature or by the available (free) volume? To answer these fundamental questions we employ some of the most common polymers exhibiting intrinsic orientational order, namely: (a) side-chain liquid crystalline polymers, (b) hairy-rod polymers and (c) synthetic polypeptides with alpha-helical secondary structure. We show that these molecularly diverse but shape-persistent macromolecules share some common features in their dynamic response. (C) 2004 Elsevier Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.progpolymsci.2004.08.004 | - |
| heal.identifier.secondary | <Go to ISI>://000225313600002 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0079670004000838/1-s2.0-S0079670004000838-main.pdf?_tid=8dd7c3d40abad4888c7efc661893ac98&acdnat=1334220363_2f1d2d82b511f6728b2539255d0a2b59 | - |
| heal.journalName | Progress in Polymer Science | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2004 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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