Synthesis and spectroscopic study of copper(II) and manganese(II) complexes with pipemidic acid
| dc.contributor.author | Szymanska, B. | en |
| dc.contributor.author | Skrzypek, D. | en |
| dc.contributor.author | Kovala-Demertzi, D. | en |
| dc.contributor.author | Staninska, M. | en |
| dc.contributor.author | Demertzis, M. A. | en |
| dc.date.accessioned | 2015-11-24T16:49:07Z | |
| dc.date.available | 2015-11-24T16:49:07Z | |
| dc.identifier.issn | 1386-1425 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9431 | |
| dc.rights | Default Licence | - |
| dc.subject | pipemidic acid (hpipem) | en |
| dc.subject | cu(ii) and mn(il) complexes | en |
| dc.subject | epr | en |
| dc.subject | interesting antiinflammatory activity | en |
| dc.subject | electron-paramagnetic resonance | en |
| dc.subject | metal-complexes | en |
| dc.subject | spin-resonance | en |
| dc.subject | crystal | en |
| dc.subject | transition | en |
| dc.subject | diclofenac | en |
| dc.subject | field | en |
| dc.subject | ions | en |
| dc.title | Synthesis and spectroscopic study of copper(II) and manganese(II) complexes with pipemidic acid | en |
| heal.abstract | The interaction of copper(II) and manganese(II) with pipemidic acid, Hpipem, afforded the complexes [Cu(pipem)(2)(H2O)](.)2H(2)O, 1 and [Mn(pipem)(2)(H2O)], 2. The new complexes have been characterised by elemental analyses, infrared, UV-vis and X-band EPR spectroscopy in the temperature range from 4 to 300 K. The monoanion, pipem, exhibits O,O ligation through the carbonyl and carboxylato oxygen atoms. Five coordinate square-pyramid configuration has been proposed for 1 and 2, and the fifth apical position is occupied by a coordinated water molecule. (c) 2005 Elsevier B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.saa.2005.05.038 | - |
| heal.identifier.secondary | <Go to ISI>://000235637000002 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S1386142505002842/1-s2.0-S1386142505002842-main.pdf?_tid=8776dff469f21335e06c8d67a093a5ea&acdnat=1333028941_f48fc458ea138c765db86e84685ea119 | - |
| heal.journalName | Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2006 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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