Mechanism of catalytic degradation of 2,4,6-trichlorophenol by a Fe-porphyrin catalyst

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dc.contributor.authorChristoforidis, K. C.en
dc.contributor.authorSerestatidou, E.en
dc.contributor.authorLouloudi, M.en
dc.contributor.authorKonstantinou, I. K.en
dc.contributor.authorMilaeva, E. R.en
dc.contributor.authorDeligiannakis, Y.en
dc.date.accessioned2015-11-24T16:41:24Z
dc.date.available2015-11-24T16:41:24Z
dc.identifier.issn0926-3373-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8414
dc.rightsDefault Licence-
dc.subjectchlorophenolen
dc.subjecttcpen
dc.subjectdcqen
dc.subjectradicalen
dc.subjectepren
dc.subjectlc-msen
dc.subjectoxidation productsen
dc.subjectdehalogenationen
dc.subjectheme catalysten
dc.subjectheterogeneous catalysten
dc.subjectcatalytic mechanismen
dc.subjectwater-soluble iron(iii)en
dc.subjectoxidative-degradationen
dc.subjectchlorinated phenolsen
dc.subjectiron tetrasulfophthalocyanineen
dc.subjecth2o2 oxidationen
dc.subjectcomplexen
dc.subjectpentachlorophenolen
dc.subjectchlorophenolsen
dc.subjectdechlorinationen
dc.subjectdehalogenationen
dc.titleMechanism of catalytic degradation of 2,4,6-trichlorophenol by a Fe-porphyrin catalysten
heal.abstractThe catalytic oxidation of 2,4,6-trichlorophenol (TCP) by a homogeneous Fe-porphyrin catalyst (FeR(4)P) and the corresponding heterogeneous one (immobilized on silica, FeR(4)P-SiO(2)) was studied by analytical and EPR spectroscopic methods. The homogeneous catalyst was found to be more efficient for oxidative decomposition and dechlorination of TCP, compared to the heterogeneous FeR(4)P-SiO(2) catalyst. The main, initial and final, oxidation products were identified and a general catalytic mechanism was proposed concerning TCP oxidation and the by-products formation, in relation with the catalyst's redox cycle. (C) 2010 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.apcatb.2010.10.011-
heal.identifier.secondary<Go to ISI>://000287068400030-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0926337310004583/1-s2.0-S0926337310004583-main.pdf?_tid=0d9fb526-362f-11e3-bcb3-00000aacb360&acdnat=1381906327_7fc66545c81fd942016af29740c1aecf-
heal.journalNameApplied Catalysis B-Environmentalen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2011-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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