Ternary Complexes of Pt(Ii) with Guanosine and Amino-Acids of the Type Trans-[(Guo)2pt(Amach)2]Cl2, Where Amach Is Glycine, L-Alanine, L-Valine, and L-Isoleucine
| dc.contributor.author | Garoufis, A. | en |
| dc.contributor.author | Hatiris, J. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.date.accessioned | 2015-11-24T16:50:03Z | |
| dc.date.available | 2015-11-24T16:50:03Z | |
| dc.identifier.issn | 0162-0134 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9562 | |
| dc.rights | Default Licence | - |
| dc.subject | dinucleoside monophosphates | en |
| dc.subject | conformational properties | en |
| dc.subject | cross-linking | en |
| dc.subject | ft-ir | en |
| dc.subject | DNA | en |
| dc.subject | nucleosides | en |
| dc.subject | cis-diamminedichloroplatinum(ii) | en |
| dc.subject | crosslinking | en |
| dc.subject | nucleotides | en |
| dc.subject | cis-pt(ii) | en |
| dc.title | Ternary Complexes of Pt(Ii) with Guanosine and Amino-Acids of the Type Trans-[(Guo)2pt(Amach)2]Cl2, Where Amach Is Glycine, L-Alanine, L-Valine, and L-Isoleucine | en |
| heal.abstract | The complexes of the general formulae trans-[(guo)2Pt(amacH)2]Cl2 with amacH = Glycine, L-Alanine, L-Valine, and L-Isoleucine, were isolated as solid adducts from the reactions of trans-[(amacH)2PtCl2] with guo in aqueous solutions. The complexes were characterized with elemental analysis, conductivity measurements, IR, and H-1 NMR spectra. Guo coordinates through N(7) and the amino acids through their-NH2 groups. Two groups of proton signals for the amino acid protons were observed in the H-1 NMR spectra, due to their participation to nonequivalent hydrogen bonds. Ligand-ligand hydrophobic interactions were detected in the complexes. The various sugar conformations of guo were calculated, based on H-1 NMR and the results were discussed in relation to DNA-Pt-protein crosslinks, taking place with cis- and trans-DDP. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1991EV19500004 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/0162013491800127/1-s2.0-0162013491800127-main.pdf?_tid=9cb3e4dac81eddf03768b1b5f16740c9&acdnat=1333029186_1060c7154f32f2310a138bcc3e6e47da | - |
| heal.journalName | J Inorg Biochem | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1991 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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